Long-chain aliphatic polymers to bridge the gap between semicrystalline polyolefins and traditional polycondensates

F Stempfle, P Ortmann, S Mecking - Chemical reviews, 2016 - ACS Publications
Other than their established short-chain congeners, polycondensates based on long-chain
difunctional monomers are often dominated by the long methylene sequences of the repeat …

Development of well-defined olefin block (co) polymers achieved by late transition metal catalysts: Catalyst, synthesis and characterization

Y Wang, J Lai, Q Gou, R Gao, G Zheng, R Zhang… - Coordination Chemistry …, 2025 - Elsevier
As the saturation rate of the bulk polyolefin market accelerates, the development of high
value-added polyolefins becomes increasingly urgent. Particular attention is directed …

Fusion of different crosslinked polymers based on dynamic disulfide exchange

A Tsuruoka, A Takahashi, D Aoki… - Angewandte …, 2020 - Wiley Online Library
Crosslinked polymers (CLPs) exhibit exceptional mechanical properties as well as good
chemical and solvent resistance. However, their reprocessing, recycling, and modification …

Chemically Recyclable Linear and Branched Polyethylenes Synthesized from Stoichiometrically Self-Balanced Telechelic Polyethylenes

YJ Jang, S Nguyen, MA Hillmyer - Journal of the American …, 2024 - ACS Publications
High-density polyethylene (HDPE) is a widely used commercial plastic due to its excellent
mechanical properties, chemical resistance, and water vapor barrier properties. However …

Melt polycondensation of carboxytelechelic polyethylene for the design of degradable segmented copolyester polyolefins

AS Arrington, JR Brown, MS Win, KI Winey… - Polymer …, 2022 - pubs.rsc.org
Chain-transfer ring-opening metathesis polymerization (CT-ROMP) previously provided a
route to carboxytelechelic polyethylene (PE) of controlled molecular weight; however, the …

Olefin cross-metathesis in polymer and polysaccharide chemistry: a review

Y Dong, JB Matson, KJ Edgar - Biomacromolecules, 2017 - ACS Publications
Olefin cross-metathesis, a ruthenium-catalyzed carbon–carbon double bond transformation
that features high selectivity, reactivity, and tolerance of various functional groups, has been …

Olefin metathesis in multiblock copolymer synthesis

ML Gringolts, YI Denisova… - Beilstein Journal of …, 2019 - beilstein-journals.org
Multiblock copolymers constitute a basis for an emerging class of nanomaterials that
combine various functional properties with durability and enhanced mechanical …

Regioselective cross metathesis for block and heterotelechelic polymer synthesis

MR Radlauer, ME Matta, MA Hillmyer - Polymer Chemistry, 2016 - pubs.rsc.org
Ring-opening metathesis polymerization (ROMP) of 3-substituted cyclooctene (3RCOE)
monomers with Grubbs 2nd and 3rd generation catalysts (G2 and G3) has been shown to …

Metathesis-driven scrambling reactions between polybutadiene or naturally occurring polyisoprene and olefin-containing polyurethane

T Ohishi, K Suyama, S Kamimura, M Sakada, K Imato… - Polymer, 2015 - Elsevier
Controlled scrambling reactions of polybutadiene and olefin-containing polyurethane
prepared by step-growth or chain-growth polymerization were accomplished via …

[HTML][HTML] Cross-metathesis of polynorbornene with polyoctenamer: A kinetic study

YI Denisova, ML Gringolts… - Beilstein journal of …, 2015 - beilstein-journals.org
The cross-metathesis of polynorbornene and polyoctenamer in d-chloroform mediated by
the 1 st generation Grubbs' catalyst Cl 2 (PCy 3) 2 Ru= CHPh is studied by monitoring the …