Isoreticular chemistry within metal–organic frameworks for gas storage and separation

W Fan, X Zhang, Z Kang, X Liu, D Sun - Coordination chemistry reviews, 2021 - Elsevier
Precise control of the pore size and environment of metal–organic framework (MOF) is a
necessary condition for achieving high performance of gas adsorption and separation. After …

Recent advances in metal–organic frameworks for gas adsorption/separation

C Jiang, X Wang, Y Ouyang, K Lu, W Jiang, H Xu… - Nanoscale …, 2022 - pubs.rsc.org
The unique structural advantage of metal–organic frameworks (MOFs) determines the great
prospect and developability in gas adsorption and separation. Both ligand design and …

Decoration and utilization of a special class of metal–organic frameworks containing the fluorine moiety

S Kumar, B Mohan, C Fu, V Gupta, P Ren - Coordination Chemistry …, 2023 - Elsevier
Fluorinated organic molecules are generally chemically stable and have low electric
polarizability because of the high electronegativity of fluorine. The use of fluorinated organic …

Amine and fluorine co-functionalized MIL-101 (Cr) synthesized via a mixed-ligand strategy for CO2 capture under humid conditions

JM Park, GY Cha, D Jo, KH Cho, JW Yoon… - Chemical Engineering …, 2022 - Elsevier
The selective capture of CO 2 in humid conditions on metal–organic frameworks is
challenging due to competitive adsorption of H 2 O and CO 2 on the active sites. Herein …

Carbon dioxide capturing activities of porous metal-organic frameworks (MOFs)

B Mohan, R Kadiyan, S Kumar, V Gupta… - Microporous and …, 2023 - Elsevier
Global warming has become a critical concern that affects the whole ecology and affects
greenhouses in the environment. Therefore, there is a great need to design and create new …

Cooperative CO 2 adsorption mechanism in a perfluorinated Ce IV-based metal organic framework

M Cavallo, C Atzori, M Signorile, F Costantino… - Journal of Materials …, 2023 - pubs.rsc.org
Adsorbents able to uptake large amounts of gases within a narrow range of pressure, ie,
phase-change adsorbents, are emerging as highly interesting systems to achieve excellent …

Cascade Dynamics of Multiple Molecular Rotors in a MOF: Benchmark Mobility at a Few Kelvins and Dynamics Control by CO2

J Perego, CX Bezuidenhout, S Bracco… - Journal of the …, 2021 - ACS Publications
Achieving sophisticated juxtaposition of geared molecular rotors with negligible energy-
requirements in solids enables fast yet controllable and correlated rotary motion to construct …

[HTML][HTML] Understanding CO2 adsorption mechanisms in porous adsorbents: A solid-state NMR survey

D Pereira, R Fonseca, I Marin-Montesinos… - Current Opinion in …, 2023 - Elsevier
Reaching a historic high of 36.3 gigatonnes in 2021, global CO 2 emissions from fossil fuel
combustion continue to increase at an alarming rate. CO 2 removal technologies are part of …

Recent advances in the chemistry and applications of fluorinated metal–organic frameworks (F-MOFs)

DM Venturi, F Costantino - RSC advances, 2023 - pubs.rsc.org
Metal–organic frameworks are a class of porous crystalline materials based on the ordered
connection of metal centers or metal clusters by organic linkers with comprehensive …

Precise fluorination of polymeric donors towards efficient non-fullerene organic solar cells with balanced open circuit voltage, short circuit current and fill factor

X Wang, H Chen, J Yuan, Q Wei, J Li, L Jiang… - Journal of Materials …, 2021 - pubs.rsc.org
Three polymer donors named Qx-8F, Qx-10F, and Qx-12F, with similar chemical structures,
were synthesized. The energy level of these donors is manipulated by precisely controlling …