Radical-polar crossover (RPC) reaction bridges the gap between one-and two-electron
reactivities, thus providing an ideal solution to overcome the limitations of both radical and …

This Minireview examines a selection of case studies that showcase distinctive and enabling
electrochemical approaches that have allowed for the generation and reaction of …

Alkoxy radicals are versatile reactive intermediates in organic synthesis. Here, we leverage
the principle of frustrated radical pair to provide convenient access to these highly reactive …

The construction of C (sp3)–heteroatom bonds represents a fundamental research field in
synthetic chemistry. We report herein an electrochemical dehydroxymethylative …

The recent resurgence of electrochemical methods in organic synthesis has also boosted
the interest in the use of flow electrolysis cells. Flow electrolyzers are essential tools for the …

Cycloalkanols ring‐opening transformation is one of the most valuable and wide area of
research. Among the numerous methods that have been developed, transition‐metal‐free …

An efficient and sustainable electrochemical method for the synthesis of cyclic ethers and
acyclic aldehydes from alkanols has been reported. This strategy has been successfully …

Herein we report an electrochemical deconstructive functionalization approach for the
synthesis of C (sp3)-rich heterocycles. The reaction proceeds via the mesolytic cleavage of …

This highlight summarises electrochemical approaches for the deconstructive
functionalization of arylcycloalkanes via the fragmentation of anodically generated aromatic …

Herein, we report a mechanistic investigation of a recently developed electrochemical
method for the deconstructive methoxylation of arylalcohols. A combination of synthetic …