Carbon nitride based materials: more than just a support for single-atom catalysis

GFSR Rocha, MAR da Silva, A Rogolino… - Chemical Society …, 2023 - pubs.rsc.org
Recently, the missing link between homogeneous and heterogeneous catalysis has been
found and it was named single-atom catalysis (SAC). However, the SAC field still faces …

A critical review on correlating active sites, oxidative species and degradation routes with persulfate-based antibiotics oxidation

N Li, J Ye, H Dai, P Shao, L Liang, L Kong, B Yan… - Water Research, 2023 - Elsevier
At present, numerous heterogeneous catalysts have been synthesized to activate persulfate
(PS) and produce various reactive species for antibiotic degradation from water. However …

Generating dual-active species by triple-atom sites through peroxymonosulfate activation for treating micropollutants in complex water

Q Zhou, C Song, P Wang, Z Zhao… - Proceedings of the …, 2023 - National Acad Sciences
The peroxymonosulfate (PMS)-triggered radical and nonradical active species can
synergistically guarantee selectively removing micropollutants in complex wastewater; …

Water decontamination via nonradical process by nanoconfined Fenton-like catalysts

T Liu, S Xiao, N Li, J Chen, X Zhou, Y Qian… - Nature …, 2023 - nature.com
There is an urgent need to develop effective and sustainable solutions to reduce water
pollution. Heterogeneous Fenton-like catalysts are frequently used to eliminate …

Ultrafast degradation of emerging organic pollutants via activation of peroxymonosulfate over Fe3C/Fe@ NCx: Singlet oxygen evolution and electron-transfer …

C Zhao, L Meng, H Chu, JF Wang, T Wang, Y Ma… - Applied Catalysis B …, 2023 - Elsevier
Abstract Fe 3 C/Fe decorated N-doped magnetic carbon materials (denoted as Fe 3 C/Fe@
NC-x) were successfully fabricated via facile one-pot calcination of MIL-88B (Fe) with a …

Unveiling the Origins of Selective Oxidation in Single-Atom Catalysis via Co–N4–C Intensified Radical and Nonradical Pathways

M Yang, Z Hou, X Zhang, B Gao, Y Li… - Environmental …, 2022 - ACS Publications
Single-atom catalysts (SACs)-based peroxymonosulfate (PMS) systems are highly selective
to the type of organic pollutants while the mechanisms remain ambiguous. In this work, we …

Electron delocalization triggers nonradical Fenton-like catalysis over spinel oxides

ZY Guo, Y Si, WQ Xia, F Wang, HQ Liu… - Proceedings of the …, 2022 - National Acad Sciences
Nonradical Fenton-like catalysis offers opportunities to overcome the low efficiency and
secondary pollution limitations of existing advanced oxidation decontamination …

A site distance effect induced by reactant molecule matchup in single‐atom catalysts for Fenton‐like reactions

B Wang, C Cheng, M Jin, J He, H Zhang… - Angewandte …, 2022 - Wiley Online Library
Understanding the site interaction nature of single‐atom catalysts (SACs), especially
densely populated SACs, is vital for their application to various catalytic reactions. Herein …

Rational Regulation of Co–N–C Coordination for High-Efficiency Generation of 1O2 toward Nearly 100% Selective Degradation of Organic Pollutants

Y Yao, C Wang, X Yan, H Zhang, C Xiao… - Environmental …, 2022 - ACS Publications
Single oxygen-based advanced oxidation processes (1O2-AOPs) exhibit great prospects in
selective degradation of organic pollutants. However, efficient production of 1O2 via tailored …

Unraveling the Mechanism on Ultrahigh Efficiency Photocatalytic H2O2 Generation for Dual‐Heteroatom Incorporated Polymeric Carbon Nitride

W Liu, P Wang, J Chen, X Gao, HN Che… - Advanced Functional …, 2022 - Wiley Online Library
Photocatalytic hydrogen peroxide (H2O2) production from dioxygen and water is regarded
as a promising technology since it can achieve sustainable and green solar‐to‐chemical …