Synthesis of biodegradable polymers: a review on the use of schiff-base metal complexes as catalysts for the ring opening polymerization (ROP) of cyclic esters
O Santoro, X Zhang, C Redshaw - Catalysts, 2020 - mdpi.com
This review describes the recent advances (from 2008 onwards) in the use of Schiff-base
metal complexes as catalysts for the ring opening polymerization (ROP) of cyclic esters. The …
metal complexes as catalysts for the ring opening polymerization (ROP) of cyclic esters. The …
Isotactic rac‐Lactide Polymerization with Copper Complexes: The Influence of Complex Nuclearity
S Fortun, P Daneshmand, F Schaper - Angewandte Chemie, 2015 - Wiley Online Library
Diiminopyrrolide copper alkoxide complexes, LCuOR (OR1= N, N‐dimethylamino ethoxide,
OR2= 2‐pyridyl methoxide), are active for the polymerization of rac‐lactide at ambient …
OR2= 2‐pyridyl methoxide), are active for the polymerization of rac‐lactide at ambient …
Mechanism and Stereocontrol in Isotactic rac-Lactide Polymerization with Copper(II) Complexes
P Daneshmand, A van der Est, F Schaper - ACS Catalysis, 2017 - ACS Publications
Reaction of NR, N′-R′-2, 5-diiminopyrroles (R= R′= S-CH (Me) Ph; R= R′= CH2Ph; R=
S-CH (Me) Ph, R′= H) with Cu (OMe) 2 in the presence of chelating alcohols, ROH (R1 …
S-CH (Me) Ph, R′= H) with Cu (OMe) 2 in the presence of chelating alcohols, ROH (R1 …
IronIII Half Salen Catalysts for Atom Transfer Radical and Ring-Opening Polymerizations
A series of monometallic pentacoordinate FeIII chloride complexes have been prepared and
characterized by high-resolution mass spectrometry and elemental analysis. X-ray diffraction …
characterized by high-resolution mass spectrometry and elemental analysis. X-ray diffraction …
Copper(II) complexes with imino phenoxide ligands: synthesis, characterization, and their application as catalysts for the ring-opening polymerization of rac-lactide
M Mandal, K Oppelt, M List, I Teasdale… - Monatshefte für Chemie …, 2016 - Springer
Four new copper complexes based on bidentate imino phenoxide ligands were synthesized
and characterized by IR, UV–Vis spectroscopy, ESI mass spectrometry, single crystal X-ray …
and characterized by IR, UV–Vis spectroscopy, ESI mass spectrometry, single crystal X-ray …
Design and catalytic studies of structural and functional models of the catechol oxidase enzyme
A Terán, A Jaafar, AE Sánchez-Peláez… - JBIC Journal of …, 2020 - Springer
The catechol oxidase activity of three copper/bicompartmental salen derivatives has been
studied. One mononuclear,[CuL](1), one homometallic,[Cu 2 L (NO 3) 2](2), and one …
studied. One mononuclear,[CuL](1), one homometallic,[Cu 2 L (NO 3) 2](2), and one …
Catalytic-Site-Mediated Chain-End Control in the Polymerization of rac-Lactide with Copper Iminopyrrolide Complexes
P Daneshmand, JL Jimenez-Santiago… - …, 2018 - ACS Publications
Reaction of copper (II) methoxide with NR-2-iminopyrroles (LH) and pyridylmethanol (R′
OH) provided the dinuclear complexes {LCu (μ-OR′)} 2 (R= naphtyl, CHPh2, 2, 6-xylyl, 2, 6 …
OH) provided the dinuclear complexes {LCu (μ-OR′)} 2 (R= naphtyl, CHPh2, 2, 6-xylyl, 2, 6 …
Coordination chemistry of [2+ 2] Schiff-base macrocycles derived from the dianilines [(2-NH 2 C 6 H 4) 2 X](X= CH 2 CH 2, O): structural studies and ROP capability …
K Wang, TJ Prior, DL Hughes, A Arbaoui… - Dalton …, 2021 - pubs.rsc.org
Reaction of the [2+ 2] Schiff-base macrocycles {[2-(OH)-5-(R)-C6H2-1, 3-(CH) 2][CH2CH2 (2-
C6H4N) 2]} 2 (R= Me, L1H2; tBu, L2H2) with FeBr2 afforded the complexes [FeBr (L1H2)] 2 …
C6H4N) 2]} 2 (R= Me, L1H2; tBu, L2H2) with FeBr2 afforded the complexes [FeBr (L1H2)] 2 …
Stereoselective polymerisation of rac-lactide catalysed by Cu (II) complexes bearing chloro derivatives of N, N′-bis (benzyl) dimethyl-(R, R)-1, 2-diaminocyclohexane
J Cho, S Nayab, JH Jeong - Polyhedron, 2016 - Elsevier
The novel Cu (II) complexes Cu (L 1) Cl 2, Cu (L 2) Cl 2, and Cu (L 3) Cl 2, where L 1 is N,
N′-bis (benzyl) dimethyl-(R, R)-1, 2-diaminocyclohexane, L 2 is N, N'-bis (o-chlorobenzyl) …
N′-bis (benzyl) dimethyl-(R, R)-1, 2-diaminocyclohexane, L 2 is N, N'-bis (o-chlorobenzyl) …
Immortal polymerization of LA: the influence of steric effects, electronic effects and p K a on chain transfer agents
N Liu, J Zhang, J Wen, X You, D Fang - Polymer Chemistry, 2022 - pubs.rsc.org
The “immortal” ring-opening polymerization (iROP) of L-LA, catalyzed by ligand-free Ca [N
(SiMe3) 2] 2 (THF) 2 in combination with different chain transfer agents (alcohols, phenols …
(SiMe3) 2] 2 (THF) 2 in combination with different chain transfer agents (alcohols, phenols …