Reversible-deactivation radical polymerization (Controlled/living radical polymerization): From discovery to materials design and applications
Reversible-deactivation radical polymerization (RDRP) processes, such as atom transfer
radical polymerization (ATRP), reversible addition-fragmentation chain transfer (RAFT) …
radical polymerization (ATRP), reversible addition-fragmentation chain transfer (RAFT) …
Linear block copolymer synthesis
Block copolymers form the basis of the most ubiquitous materials such as thermoplastic
elastomers, bridge interphases in polymer blends, and are fundamental for the development …
elastomers, bridge interphases in polymer blends, and are fundamental for the development …
Precision polymer synthesis by controlled radical polymerization: Fusing the progress from polymer chemistry and reaction engineering
During the first 100 years of polymer science, controlled radical polymerization (also
recommended as reversible deactivation radical polymerization) is undoubtedly a …
recommended as reversible deactivation radical polymerization) is undoubtedly a …
50th Anniversary Perspective: RAFT PolymerizationA User Guide
S Perrier - Macromolecules, 2017 - ACS Publications
This Perspective summarizes the features and limitations of reversible addition–
fragmentation chain transfer (RAFT) polymerization, highlighting its strengths and …
fragmentation chain transfer (RAFT) polymerization, highlighting its strengths and …
Multiblock copolymer synthesis via RAFT emulsion polymerization
A multiblock copolymer is a polymer of a specific structure that consists of multiple covalently
linked segments, each comprising a different monomer type. The control of the monomer …
linked segments, each comprising a different monomer type. The control of the monomer …
Bulk depolymerization of poly (methyl methacrylate) via chain-end initiation for catalyst-free reversion to monomer
We present the bulk depolymerization of poly (methyl methacrylate)(PMMA) at significantly
lower temperatures than previously reported methods through the incorporation of …
lower temperatures than previously reported methods through the incorporation of …
Photo‐iniferter RAFT polymerization
M Hartlieb - Macromolecular Rapid Communications, 2022 - Wiley Online Library
Light‐mediated polymerization techniques offer distinct advantages over polymerization
reactions fueled by thermal energy, such as high spatial and temporal control as well as the …
reactions fueled by thermal energy, such as high spatial and temporal control as well as the …
PET-RAFT polymerization: Mechanistic perspectives for future materials
ML Allegrezza, D Konkolewicz - ACS Macro Letters, 2021 - ACS Publications
In the past decade, photochemistry has emerged as a growing area in organic and polymer
chemistry. Use of light to drive polymerization has advantages by imparting spatial and …
chemistry. Use of light to drive polymerization has advantages by imparting spatial and …
A robust and versatile photoinduced living polymerization of conjugated and unconjugated monomers and its oxygen tolerance
Controlled/living radical polymerization techniques have transformed polymer chemistry in
the last few decades, affording the production of polymers with precise control over both …
the last few decades, affording the production of polymers with precise control over both …
Expanding the scope of RAFT polymerization: recent advances and new horizons
Reversible deactivation radical polymerization (RDRP) has revolutionized modern polymer
chemistry over the past two decades, thus laying the groundwork for the synthesis of …
chemistry over the past two decades, thus laying the groundwork for the synthesis of …