Development of melilite‐type oxide ion conductors

L Zhou, J Xu, M Allix, X Kuang - The Chemical Record, 2020 - Wiley Online Library
Lowering the operating temperature of solid oxide fuel cells (SOFCs) requires high
performance oxide ion conductor electrolytes. Recently tetrahedra‐based structures have …

Crystal Structure and Photoluminescence Evolution of La5(Si2+xB1–x)(O13–xNx):Ce3+ Solid Solution Phosphors

Z Xia, MS Molokeev, WB Im… - The Journal of Physical …, 2015 - ACS Publications
A series of iso-structural La5 (Si2+ x B1–x)(O13–x N x): Ce3+ phosphors with apatite
structure have been prepared. A combination of powder X-ray diffraction and neutron …

Amorphous Na 2 Si 2 O 5 as a fast Na+ conductor: an ab initio molecular dynamics simulation

X Lei, Y Jee, K Huang - Journal of Materials Chemistry A, 2015 - pubs.rsc.org
The present work uses the ab initio molecular dynamics (AIMD) methodology to simulate
ionic transport in amorphous and crystalline Na2Si2O5 from 573 to 973 K. The results …

Strong nano size effect of titanium silicalite (TS-1) zeolites for electrorheological fluid

X Liu, H Song, W Sun, B Wang, P Zhang, X Yuan… - Chemical Engineering …, 2020 - Elsevier
A rapid seeded growth was observed on nanosized (50–100 nm) titanium silicalite-1 (TS-1)
zeolites (denoted as nano-TS-1) with a recovered mother liquid. Only 3–8 h were required to …

Nature of conductivity in SrSiO 3-based fast ion conductors

C Tealdi, L Malavasi, I Uda, C Ferrara… - Chemical …, 2014 - pubs.rsc.org
In this paper we report the preparation and characterization of Sr1− xNaxSiO3− 0.5 x
samples, recently proposed as oxide ion conductors. We show that Na-doping unlikely takes …

On Sr1–xNaxSiO3–0.5x New Superior Fast Ion Conductors

IR Evans, JSO Evans, HG Davies… - Chemistry of …, 2014 - ACS Publications
The recent report of very high oxide ion conductivity in K-and Na-doped SrSiO3 by Singh
and Goodenough has placed these materials at the forefront of the search for promising …

Understanding the defect chemistry of alkali metal strontium silicate solid solutions: insights from experiment and theory

RD Bayliss, SN Cook, DO Scanlon, S Fearn… - Journal of Materials …, 2014 - pubs.rsc.org
Recent reports of remarkably high oxide ion conduction in a new family of strontium silicates
have been challenged. It has recently been demonstrated that, in the nominally potassium …

Influence of K+ substitution on germanium doped strontium silicate (Sr3-3xK3xSi3-3yGe3yO9-δ; 0≤ x≤ 0.20, y= 0.1) for application as solid electrolyte

H Tarique, R Shahid, P Singh, AK Singh… - Physica B: Condensed …, 2024 - Elsevier
The different alkali metal substitution strategies of the strontium meta-silicate based ion
conductors have been enormously cross-examined to synthesize cost-effective novel …

Theoretical Investigation on the Role of Na and O for High Conductivity in Na-Doped SrSiO3

F Hussain, F Zan, H Xia - The Journal of Physical Chemistry C, 2023 - ACS Publications
Generally, the conductivity of any electrolyte depends on the concentration of charge
carriers and the activation energy of mobile species in the electrolyte. The detailed …

Structural implications on transport dynamics in K-doped monomeric SrSiO3 system

R Pandey, P Singh, AN Upadhyay, R Nokhwal… - Inorganic Chemistry …, 2024 - Elsevier
Excellent ionic conductivity of alkali metal doped strontium meta silicate solid electrolytes
has widely made consideration to their usage in electrochemical devices eg solid oxide fuel …