Chemi-and bioluminescence of cyclic peroxides

M Vacher, I Fdez. Galván, BW Ding, S Schramm… - Chemical …, 2018 - ACS Publications
Bioluminescence is a phenomenon that has fascinated mankind for centuries. Today the
phenomenon and its sibling, chemiluminescence, have impacted society with a number of …

[HTML][HTML] Rearrangements of organic peroxides and related processes

IA Yaremenko, VA Vil, DV Demchuk… - Beilstein journal of …, 2016 - beilstein-journals.org
This review is the first to collate and summarize main data on named and unnamed
rearrangement reactions of peroxides. It should be noted, that in the chemistry of peroxides …

Probing force with mechanobase‐induced chemiluminescence

JM Clough, A Balan, TLJ van Daal… - Angewandte Chemie …, 2016 - Wiley Online Library
Mechanophores capable of releasing N‐heterocyclic carbene (NHC), a strong base, are
combined with triggerable chemiluminescent substrates to give a novel system for …

Fluorescent heterocycles: Recent trends and new developments

S Schramm, D Weiss - Advances in Heterocyclic Chemistry, 2019 - Elsevier
Over the last two decades fluorescent materials have strongly influenced the technological
development of modern societies. Ranging from organic photovoltaic to OLED TVs, from …

[HTML][HTML] Theoretically obtained insight into the mechanism and dioxetanone species responsible for the singlet chemiexcitation of Coelenterazine

CG Min, PJO Ferreira, LP da Silva - Journal of Photochemistry and …, 2017 - Elsevier
Coelenterazine is a widespread bioluminescent substrate for a diverse set of marine
species. Moreover, its imidazopyrazinone core is present in eight phyla of bioluminescent …

Strongly chemiluminescent acridinium esters under neutral conditions: synthesis, properties, determination, and theoretical study

M Nakazono, Y Oshikawa, M Nakamura… - The Journal of …, 2017 - ACS Publications
Various novel acridinium ester derivatives having phenyl and biphenyl moieties were
synthesized, and their optimal chemiluminescence conditions were investigated. Several …

Perspectives on bioluminescence mechanisms

J Lee - Photochemistry and Photobiology, 2017 - Wiley Online Library
The molecular mechanisms of the bioluminescence systems of the firefly, bacteria and those
utilizing imidazopyrazinone luciferins such as coelenterazine are gradually being uncovered …

Rationalizing the role of electron/charge transfer in the intramolecular chemiexcitation of dioxetanone-based chemi-/bioluminescent systems

LP da Silva, JCGE da Silva - Journal of Photochemistry and Photobiology …, 2022 - Elsevier
The thermolysis of dioxetanones is a key process in the intramolecular chemiexcitation step
of several chemi-and bioluminescent reactions. This step is generally explained with …

Tuning the polarity and surface activity of hydroxythiazoles–extending the applicability of highly fluorescent self-assembling chromophores to supra-molecular …

SH Habenicht, S Schramm, S Fischer… - Journal of Materials …, 2016 - pubs.rsc.org
A small library of N, N-diethyl-and-diethanolsulfonamides of differently substituted 2-(2-
pyridyl)-and 2-pyrazinyl-4-alkoxythiazoles has been synthesized and investigated in terms …

Elucidating the chemiexcitation of dioxetanones by replacing the peroxide bond with S–S, N–N and C–C bonds

CM Magalhaes, P González-Berdullas… - New Journal of …, 2021 - pubs.rsc.org
Dioxetanone is one of the prototypical cyclic peroxide intermediates in several
chemiluminescent and bioluminescent systems, in which thermolysis reactions allow …