Photoinduced organocatalyzed atom transfer radical polymerization (O-ATRP): precision polymer synthesis using organic photoredox catalysis

DA Corbin, GM Miyake - Chemical reviews, 2021 - ACS Publications
The development of photoinduced organocatalyzed atom transfer radical polymerization (O-
ATRP) has received considerable attention since its introduction in 2014. Expanding on …

The photophysics of photoredox catalysis: a roadmap for catalyst design

DM Arias-Rotondo, JK McCusker - Chemical Society Reviews, 2016 - pubs.rsc.org
Recently, the use of transition metal based chromophores as photo-induced single-electron
transfer reagents in synthetic organic chemistry has opened up a wealth of possibilities for …

Metal-mediated and metal-catalyzed reactions under mechanochemical conditions

A Porcheddu, E Colacino, L De Luca, F Delogu - ACS Catalysis, 2020 - ACS Publications
The extraordinary impact of metal-based complexes on synthetic methods is still recognized
nowadays, and attempts are currently undertaken to further extend the use of metal-assisted …

Swinging between shine and shadow: Theoretical advances on thermally activated vibropolaritonic chemistry

JA Campos-Gonzalez-Angulo, YR Poh, M Du… - The Journal of …, 2023 - pubs.aip.org
Polariton chemistry has emerged as an appealing branch of synthetic chemistry that
promises mode selectivity and a cleaner approach to kinetic control. Of particular interest are …

Eyringpy: A program for computing rate constants in the gas phase and in solution

E Dzib, JL Cabellos, F Ortíz‐Chi, S Pan… - … Journal of Quantum …, 2019 - Wiley Online Library
Eyringpy is a modular program for calculating thermochemical properties and rate constants
for reactions in the gas phase and in solution. The code is written in Python and it has a user …

[HTML][HTML] Polaritonic normal modes in transition state theory

JA Campos-Gonzalez-Angulo… - The Journal of chemical …, 2020 - pubs.aip.org
A series of experiments demonstrates that strong light–matter coupling between vibrational
excitations in isotropic solutions of molecules and resonant infrared optical microcavity …

The more the slower: self-inhibition in supramolecular chirality induction, memory, erasure, and reversion

J Ji, X Wei, W Wu, C Fan, D Zhou… - Journal of the …, 2022 - ACS Publications
Self-inhibition has been observed widely in hierarchical biochemical processes but has yet
to be demonstrated in pure molecular physical rather than chemical or biological processes …

Implementation and evaluation of data analysis strategies for time-resolved optical spectroscopy

C Slavov, H Hartmann, J Wachtveitl - Analytical chemistry, 2015 - ACS Publications
Time-resolved optical spectroscopy plays a key role in illuminating the mechanisms of many
fundamental processes in physics, chemistry, and biology. However, to extract the essential …

Unraveling the pivotal role of atropisomerism for cellular internalization

C Donohoe, FA Schaberle… - Journal of the …, 2022 - ACS Publications
The intrinsic challenge of large molecules to cross the cell membrane and reach intracellular
targets is a major obstacle for the development of new medicines. We report how rotation …

Influence of carbonate speciation on hydrated electron treatment processes

CK Amador, H Cavalli, R Tenorio, H Tetu… - Environmental …, 2023 - ACS Publications
Advanced reduction processes (ARPs) that generate hydrated electrons (eaq–; eg, UV-
sulfite) have emerged as a promising remediation technology for recalcitrant water …