Laser techniques for the quantitative detection of reactive intermediates in combustion systems

K Kohse-Höinghaus - Progress in Energy and Combustion Science, 1994 - Elsevier
An overview is given of recent developments in laser diagnostic methods for the quantitative
measurement of trace species concentrations and, in conjunction, of temperature in …

Ab initio potential energy surfaces and trajectory studies of A‐band photodissociation dynamics: CH3I*→ CH3+ I and CH3+ I

Y Amatatsu, K Morokuma, S Yabushita - The Journal of chemical …, 1991 - pubs.aip.org
Ab initio contracted spin-orbit configuration interaction (SOCI) calculations have been
carried out to obtain potential energy surfaces of 3Qo and IQI excited states of methyl iodide …

Methyl rotation, vibration, and alignment from a multiphoton ionization study of the 266 nm photodissociation of methyl iodide

R Ogorzalek Loo, HP Haerri, GE Hall… - The Journal of chemical …, 1989 - pubs.aip.org
The photodissociation dynamics of CH3I and CD3I have been examined by using
multiphoton ionization to probe the CH3, CD3, I (≡ 5 2 P 3/2) and I*(≡ I 5 2 P 1/2) …

Mass spectrometry of free radicals

M Sablier, T Fujii - Chemical reviews, 2002 - ACS Publications
The detection and characterization of free organic radicals has been one of the most
important challenges for mass spectrometry during the past 60 years, and, for decades, free …

Photofragment imaging: The 266 nm photodissociation of CH3I

DW Chandler, JW Thoman Jr, MHM Janssen… - Chemical physics …, 1989 - Elsevier
We use photofragment imaging to study the internal-state and velocity distributions of methyl
fragments following photodissociation of CH 3 I molecules in a pulsed molecular beam by …

Magnetic trapping of cold methyl radicals

Y Liu, M Vashishta, P Djuricanin, S Zhou, W Zhong… - Physical review …, 2017 - APS
We have demonstrated that a supersonic beam of methyl radicals (CH 3) in the ground
rotational state of both para and ortho species has been slowed down to standstill with a …

Time‐dependent dynamics of methyl iodide photodissociation in the first continuum

H Guo, GC Schatz - The Journal of chemical physics, 1990 - pubs.aip.org
The photodissociation dynamics of methyl iodide (CH3I) and its deuterated counterpart
(CD3I) in the A band is studied using a time‐dependent quantum mechanical method …

Three‐dimensional photodissociation dynamics of methyl iodide

H Guo - The Journal of chemical physics, 1992 - pubs.aip.org
The photodissociation dynamics of methyl iodide is investigated on a three‐dimensional grid
using a time‐dependent quantum‐mechanical method. Two electronic states which …

Effects of C–H stretch excitation on the H+ CH4 reaction

JP Camden, HA Bechtel, DJ Brown… - The Journal of chemical …, 2005 - pubs.aip.org
We have investigated the effects of C–H stretching excitation on the H+ CH 4→ CH 3+ H 2
reaction dynamics using the photo-LOC technique. The CH 3 product vibrational state and …

Manipulation of translational motion of methyl radicals by pulsed magnetic fields

T Momose, Y Liu, S Zhou, P Djuricanin… - Physical Chemistry …, 2013 - pubs.rsc.org
Control of the translational motion of methyl radicals is demonstrated by using pulsed
magnetic fields created by a series of solenoid coils. By synchronously switching the …