Recent advances in polyoxometalate-catalyzed reactions

SS Wang, GY Yang - Chemical reviews, 2015 - ACS Publications
Polyoxometalates (POMs) are composed of cations and polyanion clusters 1 with structural
diversity, in which the oxometal polyhedra of MOx (x= 5, 6) are the basic construction units …

Oxidative halogenation with “green” oxidants: oxygen and hydrogen peroxide

A Podgoršek, M Zupan, J Iskra - … Chemie International Edition, 2009 - Wiley Online Library
It is difficult to imagine organic chemistry without organo‐halogen compounds and the
molecular halogens needed for their preparation. The halogens have very different …

Selective C(sp3)−H Aerobic Oxidation Enabled by Decatungstate Photocatalysis in Flow

G Laudadio, S Govaerts, Y Wang, D Ravelli… - Angewandte …, 2018 - Wiley Online Library
A mild and selective C (sp3)− H aerobic oxidation enabled by decatungstate photocatalysis
has been developed. The reaction can be significantly improved in a microflow reactor …

Resin modified MIL-53 (Fe) MOF for improvement of photocatalytic performance

T Araya, M Jia, J Yang, P Zhao, K Cai, W Ma… - Applied Catalysis B …, 2017 - Elsevier
Metal organic frameworks (MOFs) are fascinating materials for diverse applications due to
their adjustability of aperture and structure. Herein, a three-dimensional iron-based MOF …

Decatungstate as an efficient photocatalyst in organic chemistry

MD Tzirakis, IN Lykakis, M Orfanopoulos - Chemical Society Reviews, 2009 - pubs.rsc.org
In view of its unique photocatalytic properties, decatungstate (W10O324−) is rapidly
emerging as a promising tool in organic chemistry. This tutorial review surveys recent …

The roles of polyoxometalates in photocatalytic reduction of carbon dioxide

J Gu, W Chen, GG Shan, G Li, C Sun, XL Wang… - Materials Today …, 2021 - Elsevier
As is well known, carbon dioxide (CO 2) reduction reaction (CO 2 RR) by photocatalytic
technology is a means with great promise to alleviate the crises on the global energy and …

Selective photocatalytic aerobic bromination with hydrogen bromide via an electron-transfer state of 9-mesityl-10-methylacridinium ion

K Ohkubo, K Mizushima, R Iwata, S Fukuzumi - Chemical science, 2011 - pubs.rsc.org
Photocatalytic bromination of aromatic hydrocarbons by molecular oxygen with hydrogen
bromide occurs efficiently to produce monobrominated products selectively using 9-mesityl …

Functional enzyme mimics for oxidative halogenation reactions that combat biofilm formation

K Herget, H Frerichs, F Pfitzner, MN Tahir… - … : Connecting Biology and …, 2020 - Springer
Chemical halogenation is an important transformation in organic synthesis. Halogenations
involve the use of reactive and toxic halogens (X 2) or hydrogen halides (HX). Chemical …

Two transition-metal-modified Nb/W mixed-addendum polyoxometalates for visible-light-mediated aerobic benzylic C–H oxidations

Y Ma, F Gao, W Xiao, N Li, S Li, B Yu, X Chen - Chinese Chemical Letters, 2022 - Elsevier
The visible-light-induced selective oxidation of ubiquitous C–H bonds into valuable C= O
bonds under aerobic conditions is one of the most attractive approaches for the construction …

A water-insoluble and visible light induced polyoxometalate-based photocatalyst

H Yang, T Liu, M Cao, H Li, S Gao, R Cao - Chemical communications, 2010 - pubs.rsc.org
A water -insoluble and visible light induced polyoxometalate-based photocatalyst - Chemical
Communications (RSC Publishing) DOI:10.1039/B919868G Royal Society of Chemistry View …