The bonding of metal-alkynyl complexes
Publisher Summary The chemistry of metal–alkynyl compounds is developing at a rapid
pace. The bonds of alkynyl ligands, like those of organic alkynes have been shown to …
pace. The bonds of alkynyl ligands, like those of organic alkynes have been shown to …
The chemistry of binuclear palladium (II) and platinum (II) complexes
VK Jain, L Jain - Coordination Chemistry Reviews, 2005 - Elsevier
The chemistry of binuclear palladium (II) and platinum (II) complexes has been reviewed.
This review deals with complexes derived from various classes of ligands and covers …
This review deals with complexes derived from various classes of ligands and covers …
Methods for the Synthesis of μ‐Hydrocarbon Transition Metal Complexes without Metal–Metal Bonds
W Beck, B Niemer, M Wieser - … Chemie International Edition in …, 1993 - Wiley Online Library
Transition metal complexes in which hydrocarbons serve as σ, σ‐, σ, π‐or π, π‐bound
bridging ligands are currently of great interest. This review presents efficient and directed …
bridging ligands are currently of great interest. This review presents efficient and directed …
Copper (I) alkyne and alkynide complexes
H Lang, A Jakob, B Milde - Organometallics, 2012 - ACS Publications
Copper(I) Alkyne and Alkynide Complexes | Organometallics ACS ACS Publications C&EN CAS
Find my institution Log In Organometallics ACS Publications. Most Trusted. Most Cited. Most …
Find my institution Log In Organometallics ACS Publications. Most Trusted. Most Cited. Most …
Bis (alkynyl) transition metal complexes, R1C C[M] C CR2, as organometallic chelating ligands; formation of μ, η1 (2)-alkynyl-bridged binuclear and …
H Lang, DSA George, G Rheinwald - Coordination Chemistry Reviews, 2000 - Elsevier
The reaction chemistry of bis (alkynyl) metal complexes towards different metal centers
(electron-rich or electron-poor) to give alkynyl-bridged binuclear and oligonuclear species is …
(electron-rich or electron-poor) to give alkynyl-bridged binuclear and oligonuclear species is …
An overview of the chemistry of homo and heteropolynuclear platinum complexes containing bridging acetylide (μ-C≡ CR) ligands
Different aspects of transition metal alkynyl chemistry have been widely studied over the
past decades because of their interesting structures, chemical reactivity and properties. This …
past decades because of their interesting structures, chemical reactivity and properties. This …
Catalytic Cyclization of o-Alkynylbenzaldehyde Acetals and Thioacetals. Unprecedented Activation of the Platinum Catalyst by Olefins. Scope and Mechanism of the …
I Nakamura, GB Bajracharya, H Wu… - Journal of the …, 2004 - ACS Publications
A general protocol for the synthesis of functionalized indenes from o-alkynylbenzaldehyde
acetals and thioacetals has been elaborated. Acetals uniformly give cyclization products …
acetals and thioacetals has been elaborated. Acetals uniformly give cyclization products …
Stereo-and regioselective dimerization of alkynes to enynes by bimetallic syn-carbopalladation
C Pfeffer, N Wannenmacher, W Frey, R Peters - ACS Catalysis, 2021 - ACS Publications
Enynes are important motifs in bioactive compounds. They can be synthesized by alkyne–
alkyne couplings for which a number of mechanisms have been suggested depending on …
alkyne couplings for which a number of mechanisms have been suggested depending on …
Preparation and Properties of trans-Pd(Ar)(C⋮CPh)(PEt3)2. Intermolecular Alkynyl Ligand Transfer between Copper(I) and Palladium(II) Complexes Relevant to …
K Osakada, R Sakata, T Yamamoto - Organometallics, 1997 - ACS Publications
trans-Pd (C6H4Me-p)(I)(PEt3) 2 (2a) reacts with [Cu (C⋮ CPh)(PPh3)] 4 (Pd: Cu= 1: 1) at
room temperature to give the cross-coupling product PhC⋮ CC6H4Me-p (3a) in 74% yield …
room temperature to give the cross-coupling product PhC⋮ CC6H4Me-p (3a) in 74% yield …
Double addition of phenylacetylene onto the mixed bridge phosphinito–phosphanido Pt (i) complex [(PHCy 2) Pt (μ-PCy 2){κ 2 P, O-μ-P (O) Cy 2} Pt (PHCy 2)](Pt–Pt)
The reaction of the dinuclear phosphinito bridged complex [(PHCy2) Pt (μ-PCy2){κ2P, O-μ-P
(O) Cy2} Pt (PHCy2)](Pt–Pt)(1) with phenylacetylene affords the η1-alkenyl-μ, η1: η2-alkynyl …
(O) Cy2} Pt (PHCy2)](Pt–Pt)(1) with phenylacetylene affords the η1-alkenyl-μ, η1: η2-alkynyl …