Direct and rapid heating by microwave irradiation in combination with sealed vessel
processing in many cases enables reactions to be carried out in a fraction of the time …

Though often perceived as the simple metaphorical hybrid of synthetic inorganic and
organic chemistry, synthetic organometallic chemistry continues to vigorously differentiate …

Herein, we describe a solvent-and metal-free method for the synthesis of 3-chalcogenyl-
indoles from indoles and diorganyl dichalcogenides using an equivalent amount of DMSO …

Triarylmethanes are attractive targets because of their applications in medicinal and
materials chemistry.[1–7] For example, several triarylmethanes have emerged as promising …

Secondary benzylic ethers undergo stereospecific substitution reactions with Grignard
reagents in the presence of nickel catalysts. Reactions proceed with inversion of …

Alkyl Grignard reagents that contain β‐hydrogen atoms were used in a stereospecific nickel‐
catalyzed cross‐coupling reaction to form C (sp3) C (sp3) bonds. Aryl Grignard reagents …

The present research focuses on a Ni-Mg-Al hydrotalcite-derived catalyst promoted with Cu.
Catalysts were prepared by the co-precipitation method at constant pH and were …

The first Negishi nickel-catalyzed stereospecific cross-coupling reaction of secondary
benzylic esters is reported. A series of traceless directing groups is evaluated for ability to …

Abstract Reductive desymmetrization of 2, 2-disubstituted prochiral 1, 3-cyclodiketones to 2,
2-disubstituted-3-hydroxycycloketones is a highly desired transformation for the construction …

We report a Rh-catalyzed, enantioselective silylation of arene C–H bonds directed by a
(hydrido) silyl group.(Hydrido) silyl ethers that are formed in situ by hydrosilylation of …