The chiral oxazoline motif is present in many ligands that have been extensively applied in a
series of important metal-catalyzed enantioselective reactions. This Review aims to provide …

Oxazoline-containing ligands have been widely employed in numerous asymmetric catalytic
reactions. Pyridine-oxazoline-type ligands, a class of hybrid ligands, were designed earlier …

Heck reaction is one of the most important carbon‐carbon bond forming reactions with wide
applications in organic synthesis. Considerable advances of enantioselective Heck reaction …

Despite the importance of P-chiral organophosphorus compounds in asymmetric catalysis,
transition metal-catalyzed methods for accessing P-chiral phosphine derivatives are still …

Unprecedented enantioselective intramolecular Heck carbonylation reactions of
arenediazonium salts were enabled by a chiral N, N ligand. This reaction constitutes the first …

An approach has been developed for the enantioselective synthesis of P-chiral phosphine
oxides bearing an all-carbon quaternary stereogenic center via a Pd-catalyzed domino Heck …

Cyclic sulfones have demonstrated important applications in drug discovery. However, the
catalytic and enantioselective synthesis of chiral cyclic sulfones remains challenging …

The use of more than one catalyst in one-pot reaction conditions has become a rapidly
evolving protocol in the development of asymmetric catalysis. The lack of molecular insights …

Indole-fused bicyclo [3.2. 1] octanes are highly important structural units in natural products
and biologically active compounds. However, there has been limited success in the …

Saturated heterocycles, which incorporate S and O heteroatoms, serve as fundamental
frameworks in a diverse array of natural products, bioactive compounds, and …