Rare-earth based tetrapyrrolic sandwiches: chemistry, materials and applications

AG Martynov, Y Horii, K Katoh, Y Bian, J Jiang… - Chemical Society …, 2022 - pubs.rsc.org
The unique properties of natural tetrapyrrolic compounds have inspired the rapid growth of
research interest in the design and synthesis of artificial porphyrinoids and their metal …

Lanthanide Single‐molecule Magnets: Synthetic Strategy, Structures, Properties and Recent Advances

J Wang, CY Sun, Q Zheng, DQ Wang… - Chemistry–An Asian …, 2023 - Wiley Online Library
Single‐molecule magnets (SMMs) show wide potential applications in the field of ultrahigh‐
density storage materials, quantum computing, spintronics, and so on. Lanthanide (Ln) …

Dysprosium (III) metal–organic framework demonstrating ratiometric luminescent detection of pH, magnetism, and proton conduction

FG Chen, W Xu, J Chen, HP Xiao, HY Wang… - Inorganic …, 2022 - ACS Publications
A multifunctional metal–organic framework,(Hdmbpy)[Dy (H2dobdc) 2 (H2O)]· 3H2O (Dy-
MOF, H4dobdc= 2, 5-dihydroxyterephthalic acid, dmbpy= 4, 4′-dimethyl-2, 2′-bipyridine) …

Effect of bridging ligands on magnetic behavior in dinuclear dysprosium cores supported by polyoxometalates

Y Huo, YC Chen, SG Wu, JL Liu, JH Jia… - Inorganic …, 2018 - ACS Publications
A family of dinuclear dysprosium cores bridged by different ligands within a
polyoxometalates (POMs) framework,(TBA) 8.5 H1. 5 [(PW11O39) 2Dy2X2 (H2O) 2]· 6H2O …

Synthesis, characterization, photoluminescence properties and cytotoxic activities of Sm (III) complexes of β-diketones

AO Sarıoğlu, DT Kahraman, A Köse… - Journal of Molecular …, 2022 - Elsevier
Three new homoleptic six-coordinate Sm (III) complexes have been synthesized from β-
diketone ligand with different substituent groups. The structural characterization of these …

Influence of the Coordinated Transition Metal Ion on Magnetic Relaxation of Lanthanide Based Complexes with Imino Nitroxide Biradical Ligands

L Xi, C Jin, H Song, X Wang, J Xie, Y Ma… - … A European Journal, 2022 - Wiley Online Library
In spite of achievement of a lot of Ln‐radical SMMs, how to improve magnetic behavior of Ln‐
radical system remains challenging. Here, two series of Ln‐radical complexes have …

Macrocycle supported dinuclear lanthanide complexes with different β-diketonate co-ligands displaying zero field single-molecule magnetic behaviour

K Pramanik, YC Sun, P Brandão, NC Jana… - New Journal of …, 2022 - pubs.rsc.org
Three different sets of isomorphous dinuclear Gd/Dy complexes,[Ln2 (L′)(acac) 4]· 2H2O·
2CH3CN (Ln= Gd (1Gd) and Dy (2Dy); acac= acetylacetonate),[Ln2 (L′)(tfac) 4](Ln= Gd …

Fabricating Bis (phthalocyaninato) Terbium SIM into Tetrakis (phthalocyaninato) Terbium SMM with enhanced performance through sodium coordination

Y Chen, C Liu, F Ma, D Qi, Q Liu… - … –A European Journal, 2018 - Wiley Online Library
Abstract The non‐peripherally substituted 1, 4, 8, 11, 15, 18, 22, 25‐octa (butoxy)‐
phthalocyanine‐involved unsymmetrical heteroleptic bis (phthalocyaninato) terbium double …

Evolution from a single relaxation process to two-step relaxation processes of Dy 2 single-molecule magnets via the modulations of the terminal solvent ligands

D Li, MM Ding, Y Huang, DFT Yepes, H Li, Y Li… - Dalton …, 2021 - pubs.rsc.org
To explore the influences of magnetic interactions on the relaxation dynamics of single-
molecule magnets (SMMs) and to understand the relationship between single-ion relaxation …

Magnetic, fluorescence and electric properties of rare earth complexes based on reduced Schiff base carboxylic acid ligand

LZ Yang, RX Yang, PY Zhu, TC Yue, YM Yu… - Journal of Molecular …, 2023 - Elsevier
By regulating the reaction system, two kinds of rare earth complexes [M (L)(HL)(DMF)] n [M=
Eu (1), Nd (2), Pr (3) and [M (L)(HL)(H 2 O) 3] n [M= Eu (4), Ho (5), Dy (6), Er (7), Y (8)] with …