Construction and application of base-stable MOFs: a critical review
Metal–organic frameworks (MOFs) are a new class of porous crystalline materials
constructed from organic ligands and metal ions/clusters. Owing to their unique advantages …
constructed from organic ligands and metal ions/clusters. Owing to their unique advantages …
Metal–organic framework (MOF)-, covalent-organic framework (COF)-, and porous-organic polymers (POP)-catalyzed selective C–H bond activation and …
Although C–H functionalization is one of the simplest reactions, it requires the use of highly
active and selective catalysts. Recently, C–H-active transformations using porous materials …
active and selective catalysts. Recently, C–H-active transformations using porous materials …
Single-atom yttrium engineering janus electrode for rechargeable Na–S batteries
The development of rechargeable Na–S batteries is very promising, thanks to their
considerably high energy density, abundance of elements, and low costs and yet faces the …
considerably high energy density, abundance of elements, and low costs and yet faces the …
MOF-enabled confinement and related effects for chemical catalyst presentation and utilization
A defining characteristic of nearly all catalytically functional MOFs is uniform, molecular-
scale porosity. MOF pores, linkers and nodes that define them, help regulate reactant and …
scale porosity. MOF pores, linkers and nodes that define them, help regulate reactant and …
Self-adaptive dual-metal-site pairs in metal-organic frameworks for selective CO2 photoreduction to CH4
Solar-light-driven reduction of CO2-to-CH4 is a complex process involving multiple
elementary reactions and various by-products. Achieving high CH4 activity and selectivity …
elementary reactions and various by-products. Achieving high CH4 activity and selectivity …
Direct photo-oxidation of methane to methanol over a mono-iron hydroxyl site
Natural gas, consisting mainly of methane (CH4), has a relatively low energy density at
ambient conditions (~ 36 kJ l− 1). Partial oxidation of CH4 to methanol (CH3OH) lifts the …
ambient conditions (~ 36 kJ l− 1). Partial oxidation of CH4 to methanol (CH3OH) lifts the …
Metal–organic frameworks in heterogeneous catalysis: recent progress, new trends, and future perspectives
More than 95%(in volume) of all of today's chemical products are manufactured through
catalytic processes, making research into more efficient catalytic materials a thrilling and …
catalytic processes, making research into more efficient catalytic materials a thrilling and …
“Ship-in-a-Bottle” Integration of Ditin(IV) Sites into a Metal–Organic Framework for Boosting Electroreduction of CO2 in Acidic Electrolyte
H Xue, ZH Zhao, PQ Liao, XM Chen - Journal of the American …, 2023 - ACS Publications
The electrochemical CO2 reduction reaction (eCO2RR) under acidic conditions has become
a promising way to achieve high CO2 utilization because of the inhibition of undesirable …
a promising way to achieve high CO2 utilization because of the inhibition of undesirable …
Metal–organic framework-based catalysts with single metal sites
Metal–organic frameworks (MOFs) are a class of distinctive porous crystalline materials
constructed by metal ions/clusters and organic linkers. Owing to their structural diversity …
constructed by metal ions/clusters and organic linkers. Owing to their structural diversity …
Engineering single-atom sites into pore-confined nanospaces of porphyrinic metal–organic frameworks for the highly efficient photocatalytic hydrogen evolution …
Q Mo, L Zhang, S Li, H Song, Y Fan… - Journal of the American …, 2022 - ACS Publications
As a type of heterogeneous catalyst expected for the maximum atom efficiency, a series of
single-atom catalysts (SACs) containing spatially isolated metal single atoms (M-SAs) have …
single-atom catalysts (SACs) containing spatially isolated metal single atoms (M-SAs) have …