Polyoxometalates (POMs): from electroactive clusters to energy materials
Polyoxometalates (POMs) represent a class of nanomaterials, which hold enormous
promise for a range of energy-related applications. Their promise is owing to their “special” …
promise for a range of energy-related applications. Their promise is owing to their “special” …
Molecular and heterogeneous water oxidation catalysts: recent progress and joint perspectives
The development of reliable water oxidation catalysts (WOCs) is essential for implementing
artificial photosynthesis on a large technological scale. WOC research has evolved into two …
artificial photosynthesis on a large technological scale. WOC research has evolved into two …
Recent advances in polyoxometalate-catalyzed reactions
SS Wang, GY Yang - Chemical reviews, 2015 - ACS Publications
Polyoxometalates (POMs) are composed of cations and polyanion clusters 1 with structural
diversity, in which the oxometal polyhedra of MOx (x= 5, 6) are the basic construction units …
diversity, in which the oxometal polyhedra of MOx (x= 5, 6) are the basic construction units …
Frontiers of water oxidation: the quest for true catalysts
Development of efficient and economic water oxidation catalysts (WOCs) remains a crucial
bottleneck on the way to artificial photosynthesis applications. Over the past few decades …
bottleneck on the way to artificial photosynthesis applications. Over the past few decades …
In situ X-ray absorption spectroscopy of transition metal based water oxidation catalysts
CHM van Oversteeg, HQ Doan… - Chemical Society …, 2017 - pubs.rsc.org
X-ray absorption studies of the geometric and electronic structure of primarily
heterogeneous Co, Ni, and Mn based water oxidation catalysts are reviewed. The X-ray …
heterogeneous Co, Ni, and Mn based water oxidation catalysts are reviewed. The X-ray …
An exceptionally fast homogeneous carbon-free cobalt-based water oxidation catalyst
An all-inorganic, oxidatively and thermally stable, homogeneous water oxidation catalyst
based on redox-active (vanadate (V)-centered) polyoxometalate ligands, Na10 [Co4 (H2O) …
based on redox-active (vanadate (V)-centered) polyoxometalate ligands, Na10 [Co4 (H2O) …
A noble-metal-free, tetra-nickel polyoxotungstate catalyst for efficient photocatalytic hydrogen evolution
A tetra-nickel-containing polyoxotungstate, Na6K4 [Ni4 (H2O) 2 (PW9O34) 2]· 32H2O
(Na6K4-Ni 4 P 2), has been synthesized in high yield and systematically characterized. The …
(Na6K4-Ni 4 P 2), has been synthesized in high yield and systematically characterized. The …
Polyoxometalate‐Structured Materials: Molecular Fundamentals and Electrocatalytic Roles in Energy Conversion
Polyoxometalates (POMs), a kind of molecular metal oxide cluster with unique physical–
chemical properties, have made essential contributions to creating efficient and robust …
chemical properties, have made essential contributions to creating efficient and robust …
Polyoxometalate‐Based Single‐Atom Catalyst with Precise Structure and Extremely Exposed Active Site for Efficient H2 Evolution
ZR Zhang, HY Sui, WX Shi, J Ren, S Yao… - Angewandte Chemie …, 2024 - Wiley Online Library
Single‐atom catalysts with precise structure and extremely high catalytic efficiency remain a
fervent focus in the fields of materials chemistry and catalytic science. Herein, a nickel …
fervent focus in the fields of materials chemistry and catalytic science. Herein, a nickel …
Photo-Electrochemical Effect in the Amorphous Cobalt Oxide Water Oxidation Catalyst Cobalt–Phosphate (CoPi)
EA Sprague-Klein, X He, MW Mara… - ACS Energy …, 2022 - ACS Publications
The cobalt–phosphate amorphous oxyhydroxide water-splitting catalyst, CoPi, is widely
investigated because of its reactivity and self-repair analogous to the oxygen-evolving …
investigated because of its reactivity and self-repair analogous to the oxygen-evolving …