Polyoxometalates (POMs): from electroactive clusters to energy materials

MR Horn, A Singh, S Alomari… - Energy & …, 2021 - pubs.rsc.org
Polyoxometalates (POMs) represent a class of nanomaterials, which hold enormous
promise for a range of energy-related applications. Their promise is owing to their “special” …

Molecular and heterogeneous water oxidation catalysts: recent progress and joint perspectives

J Li, CA Triana, W Wan, DPA Saseendran… - Chemical Society …, 2021 - pubs.rsc.org
The development of reliable water oxidation catalysts (WOCs) is essential for implementing
artificial photosynthesis on a large technological scale. WOC research has evolved into two …

Recent advances in polyoxometalate-catalyzed reactions

SS Wang, GY Yang - Chemical reviews, 2015 - ACS Publications
Polyoxometalates (POMs) are composed of cations and polyanion clusters 1 with structural
diversity, in which the oxometal polyhedra of MOx (x= 5, 6) are the basic construction units …

Frontiers of water oxidation: the quest for true catalysts

J Li, R Güttinger, R Moré, F Song, W Wan… - Chemical Society …, 2017 - pubs.rsc.org
Development of efficient and economic water oxidation catalysts (WOCs) remains a crucial
bottleneck on the way to artificial photosynthesis applications. Over the past few decades …

In situ X-ray absorption spectroscopy of transition metal based water oxidation catalysts

CHM van Oversteeg, HQ Doan… - Chemical Society …, 2017 - pubs.rsc.org
X-ray absorption studies of the geometric and electronic structure of primarily
heterogeneous Co, Ni, and Mn based water oxidation catalysts are reviewed. The X-ray …

An exceptionally fast homogeneous carbon-free cobalt-based water oxidation catalyst

H Lv, J Song, YV Geletii, JW Vickers… - Journal of the …, 2014 - ACS Publications
An all-inorganic, oxidatively and thermally stable, homogeneous water oxidation catalyst
based on redox-active (vanadate (V)-centered) polyoxometalate ligands, Na10 [Co4 (H2O) …

A noble-metal-free, tetra-nickel polyoxotungstate catalyst for efficient photocatalytic hydrogen evolution

H Lv, W Guo, K Wu, Z Chen, J Bacsa… - Journal of the …, 2014 - ACS Publications
A tetra-nickel-containing polyoxotungstate, Na6K4 [Ni4 (H2O) 2 (PW9O34) 2]· 32H2O
(Na6K4-Ni 4 P 2), has been synthesized in high yield and systematically characterized. The …

Polyoxometalate‐Structured Materials: Molecular Fundamentals and Electrocatalytic Roles in Energy Conversion

T Ma, R Yan, X Wu, M Wang, B Yin, S Li… - Advanced …, 2024 - Wiley Online Library
Polyoxometalates (POMs), a kind of molecular metal oxide cluster with unique physical–
chemical properties, have made essential contributions to creating efficient and robust …

Polyoxometalate‐Based Single‐Atom Catalyst with Precise Structure and Extremely Exposed Active Site for Efficient H2 Evolution

ZR Zhang, HY Sui, WX Shi, J Ren, S Yao… - Angewandte Chemie …, 2024 - Wiley Online Library
Single‐atom catalysts with precise structure and extremely high catalytic efficiency remain a
fervent focus in the fields of materials chemistry and catalytic science. Herein, a nickel …

Photo-Electrochemical Effect in the Amorphous Cobalt Oxide Water Oxidation Catalyst Cobalt–Phosphate (CoPi)

EA Sprague-Klein, X He, MW Mara… - ACS Energy …, 2022 - ACS Publications
The cobalt–phosphate amorphous oxyhydroxide water-splitting catalyst, CoPi, is widely
investigated because of its reactivity and self-repair analogous to the oxygen-evolving …