We demonstrate Markovnikov hydroalkoxylation of unactivated alkenes using alcohols
through a triple catalysis consisting of photoredox, cobalt, and Brønsted acid catalysts under …

A Markovnikov-selective hydroacylation of alkenes has been achieved via the synergistic
merger cobalt, photoredox and N-heterocyclic carbene catalysis. The closely incorporated …

We demonstrate hydrohalogenation of aliphatic alkenes with collidine· HX salts through dual
photoredox/cobalt catalysis. The dual catalysis enables conversion of a proton and a halide …

We report herein an asymmetric C–H dehydrogenative allylic alkylation by a synergistic
catalytic system involving a chiral primary amine, a photoredox catalyst, and a cobaloxime …

Abstract α-Tertiary amides are of great importance for medicinal chemistry. However, they
are often challenging to access through conventional methods due to reactivity and …

A cobalt‐catalyzed intramolecular Markovnikov hydroalkoxycarbonylation and
hydroaminocarbonylation of unactivated alkenes has been developed, enabling highly …

Cobalt-mediated radical polymerization (CMRP) is a versatile technique for controlling the
polymerization of vinyl monomers via reversible termination using CoII complexes as …

We report herein a visible light-mediated direct deuteration of alkenes with D2O or
deuterated methanol (MeOD) using a cobaloxime as a hydrogen/deuterium (H/D) exchange …

A general protocol has been developed for the Markovnikov-selective intermolecular
hydrofunctionalization based on visible-light-mediated Co/Ru dual catalysis. The key feature …

In metal hydride-catalyzed alkene hydrofunctionalization reactions via hydrogen atom
transfer, simple carbonyl groups have been well-recognized as good somophiles at the …