Organic materials with radical characteristics are gaining increasing attention, due to their
potential implications in highly efficient utilization of solar energy. Manipulating …

The diradical character in a molecular architecture can be customized primarily in two ways:
first, by employing a quinoidal pro-aromatic system with net energy gained by aromatization …

Herein we report the synthesis and characterization of anionic boron-and carbon-based
Kekulé diradicaloids spanned by ap-phenylene bridge. In contrast to Thiele's hydrocarbon, a …

Metal–organic frameworks (MOFs) can respond to light in a number of interesting ways.
Photochromism is observed when a structural change to the framework is induced by the …

Spin–Spin interactions between unpaired electrons in organic radicals are of utter
importance from the viewpoint of molecular magnetism and the development of smart …

We report a one-pot synthesis of a series of unprecedented angular-fused diaza-
dinaphthopyrene isomers (1, 8-DNPy and 1, 6-DNPy) in high yields, which are enabled by …

Abstract Acenes and Naphthalene Diimides (NDIs) stand as distinguished classes of
organic compounds, each possessing unique and intriguing properties that have garnered …

Stable metal‐free diradicaloids are fascinating compounds, typically based on covalent
polycyclic or nitrogen‐containing π‐conjugated frameworks. Unfortunately, their preparation …

Herein, we report the syntheses and electronic structures of crystalline dianionic as well as
neutral diboron-centered classical diradicaloids as boron analogues of classical Thiele …

Derived from the lateral fusion of benzene rings, acenes are a class of π-conjugated
molecules containing a single aromatic sextet, where system size is inversely correlated with …