Low valent coinage metal coordination compounds with group 15, 16 and 17 donors

PD Akrivos, HJ Katsikis, A Koumoutsi - Coordination chemistry reviews, 1997 - Elsevier
The advances made during the decade following 1985 in the coordination chemistry of
monovalent group 11 metals with ligands possessing donor atoms from groups 15, 16 and …

1‐Alkynylphosphines and their derivatives as key starting materials in creating new phosphines

A Kondoh, H Yorimitsu, K Oshima - Chemistry–An Asian …, 2010 - Wiley Online Library
Abstract This Focus Review summarizes transformations of 1‐alkynylphosphines and their
derivatives directed toward the synthesis of new phosphines. Owing to the importance of …

(p-cymene)Ruthenium(II)(diphenylphosphino)alkyne Complexes:  Preparation of (μ-Cl)(μ-PPh2C⋮CR)-Bridged Ru/Pt Heterobimetallic Complexes

JR Berenguer, M Bernechea, J Forniés, A García… - …, 2004 - ACS Publications
The neutral complexes [(η6-p-cymene) RuCl2 (PPh2C⋮ CR)](R= Ph 1, tBu 2,(4-CH3) C6H4
3,(4-C⋮ CPh) C6H4 4,(4-CN) C6H4 5) have been synthesized by reacting [(p-cymene) …

Pathways to Polynuclear Complexes with α-S,N-Substituted Alkynes as Bridging Ligands

J Rüger, C Timmermann, A Villinger… - Inorganic …, 2019 - ACS Publications
Recently, alkyne complexes with terminal thiolate/amide substitution have been shown to
act as S, N-chelate ligands in dinuclear complexes. In this study, the detailed synthesis and …

Formation of Diphenylphosphanylbutadienyl Complexes by Insertion of Two P‐Coordinated Alkynylphosphanes into a PtC6F5 Bond: Detection of Intermediate and …

I Ara, J Forniés, A García, J Gómez… - … A European Journal, 2002 - Wiley Online Library
The reactions between cis‐[M (C6F5) 2 (PPh2C CR) 2](M= Pt, Pd; R= Ph, tBu, Tol 2, 3) or
cis‐[Pt (C6F5) 2 (PPh2C CR)(PPh2C CtBu)](R= Ph 4, Tol 5) and cis‐[Pt (C6F5) 2 (thf) 2] 1 …

Diphenyl(phenylethynyl)phosphine d6 [Rh(III), Ir(III), Ru(II)] Complexes:  Preparation of Homo (μ-Cl)2 and Hetero (μ-Cl)(μ-PPh2C⋮CPh) Bridged d6−d8 …

JR Berenguer, M Bernechea, J Forniés, J Gómez… - …, 2002 - ACS Publications
The novel P-coordinated diphenyl (phenylethynyl) phosphine complexes [Cp* MCl2
(PPh2C⋮ CPh)][M= Rh 1, Ir 2] have been prepared by the bridge splitting of [Cp* MCl2] 2 …

Reactivity of an acetylenephosphino gold (III) precursor: Addition to the triple bond or formation of alkynyl derivatives

M Bardají, A Laguna, PG Jones - Organometallics, 2001 - ACS Publications
We have synthesized the gold (III) complex Au (C6F5) 3 (PPh2CCH)(1), containing an
acetylene moiety. Reactions with sodium alkoxides lead chemoselectively and …

Alkynyldiphenylphosphine d8 (Pt, Rh, Ir) Complexes:  Contrasting Behavior toward cis-[Pt(C6F5)2(THF)2]

JR Berenguer, M Bernechea, J Forniés… - Inorganic …, 2004 - ACS Publications
The synthesis and characterization of a series of mononuclear d8 complexes with at least
two P-coordinated alkynylphosphine ligands and their reactivity toward cis-[Pt (C6F5) 2 …

Facile Single or Double C− H Bond Activation on a Cp* Ligand Promoted by the Presence of Alkynylphosphine Ligands

M Bernechea, JR Berenguer, E Lalinde… - Organometallics, 2009 - ACS Publications
The behavior of the cationic alkynylphosphine complex [Rh (η5-Cp*) Cl (PPh2C CPh)
2](CF3SO3)(1) under thermal or basic conditions is described. Complex 1 rearranges …

Unprecedented reversible coupling of alkynyl and phosphide ligands on a dinuclear platinum framework

A Albinati, V Filippi, P Leoni, L Marchetti… - Chemical …, 2005 - pubs.rsc.org
Unprecedented reversible coupling of alkynyl and phosphide ligands on a dinuclear platinum
framework - Chemical Communications (RSC Publishing) DOI:10.1039/B418893D Royal …