Unifying nonlinear response and incoherent mixing in action-2D electronic spectroscopy

M Bruschi, L Bolzonello, F Gallina… - The Journal of Physical …, 2023 - ACS Publications
Action-detection has expanded the scope and applicability of 2D electronic spectroscopy,
while posing new challenges for the unambiguous interpretation of spectral features. In this …

Nonlinear Optical Spectroscopy of Molecular Assemblies: What Is Gained and Lost in Action Detection?

L Bolzonello, M Bruschi, B Fresch… - The Journal of Physical …, 2023 - ACS Publications
This study elucidates the information content that is extracted from action-2D electronic
spectroscopy (A-2DES) when the output intensity is not proportional to the number of …

A Quantum Algorithm from Response Theory: Digital Quantum Simulation of Two-Dimensional Electronic Spectroscopy

M Bruschi, F Gallina, B Fresch - The Journal of Physical Chemistry …, 2024 - ACS Publications
Multidimensional optical spectroscopies are powerful techniques to investigate energy
transfer pathways in natural and artificial systems. Because of the high information content of …

Photosynthetic energy transfer: Missing in action (detected spectroscopy)?

A Javed, J Lüttig, K Charvátová… - The Journal of …, 2024 - ACS Publications
In recent years, action-detected ultrafast spectroscopies have gained popularity offering
distinct advantages over their coherently detected counterparts, such as spatially resolved …

Photoelectrochemical Two-Dimensional Electronic Spectroscopy (PEC2DES) of Photosystem I: Charge Separation Dynamics Hidden in a Multichromophoric …

M López-Ortiz, L Bolzonello, M Bruschi… - … Applied Materials & …, 2024 - ACS Publications
We present a nonlinear spectroelectrochemical technique to investigate photosynthetic
protein complexes. The PEC2DES setup combines photoelectrochemical detection (PEC) …

Expanding the bandwidth of fluorescence-detected two-dimensional electronic spectroscopy using a broadband continuum probe pulse pair

SE Sanders, M Zhang, A Javed, JP Ogilvie - Optics Express, 2024 - opg.optica.org
We demonstrate fluorescence-detected two-dimensional electronic spectroscopy (F-2DES)
with a broadband, continuum probe pulse pair in the pump-probe geometry. The approach …

Coherent Vibrations Promote Charge-Transfer across a Graphene-Based Interface

A Casotto, PS Rukin, E Fresch, D Prezzi… - Journal of the …, 2024 - ACS Publications
Discerning the impact of the coherent motion of the nuclei on the timing and efficiency of
charge transfer at the donor–acceptor interface is essential for designing performance …

A spectrometer design that eliminates incoherent mixing signals in 2D action spectroscopies

ZM Faitz, D Im, CJ Blackwell, MS Arnold… - The Journal of Chemical …, 2024 - pubs.aip.org
Action spectroscopies use a readout created by the action of light on the molecules or
material rather than optical absorption. Ultrafast 2D photocurrent and 2D fluorescence …

Compact modeling of Highly excited linear aggregates using generalized quantum particles

V Bubilaitis, D Abramavicius - Chemical Physics, 2025 - Elsevier
Calculation of nonlinear spectra of chromophore aggregates using response function theory
when the number of contributing chromophores is large, and the level of excitation is high is …

Direct Visualization of Confinement and Many‐Body Correlation Effects in 2D Spectroscopy of Quantum Dots

E Amarotti, Z Wang, A Hedse… - Advanced Optical …, 2024 - Wiley Online Library
The size tunable color of colloidal semiconductor quantum dots (QDs) is probably the most
elegant illustration of the quantum confinement effect. As explained by the simple “particle …