Superoxide, O2•−, is formed in all living organisms that come in contact with air, and,
depending upon its biological context, it may act as a signaling agent, a toxic species, or a …

Pulse radiolysis is a powerful method for generating highly reduced or oxidized species and
free radicals. Combined with fast time-resolved spectroscopic measurement, we can monitor …

In the present work the oxidation of ferrocene, Fe (C 5 H 5) 2, to the ferrocenium cation, Fe
(C 2 H 5) 2+, was examined in the solvents acetonitrile (ACN), acetone (ACE), N …

The imidazolate-bridged dinuclear copper (II)(1) and the imidazolate-bridged
heterodinuclear copper (II)—zinc (II)(2) complexes of a macrobicyclic ligand L (L= l, 4, 12 …

A library of complexes that included iron, cobalt, nickel, and copper chelates of cyclam,
cyclen, DOTA, DTPA, EDTA, tripeptide GGH, tetrapeptide KGHK, NTA, and TACN was …

A new dinucleating ligand, 1, 5-bis (1-pyrazolyl)-3-[bis (2-imidazolyl) methyl] azapentane
(Hbpzbiap), containing pyrazoles and imidazoles has been designed and synthesized. The …

Publisher Summary This chapter discusses structure and properties of copper–zinc
superoxide dismutases. The superoxide radical anion is physiologically produced in …

The mechanism for the toxic superoxide radical disproportionation to molecular oxygen and
hydrogen peroxide by copper− zinc superoxide dismutase (CuZnSOD) has been studied …

Here, we report on a novel superoxide anion (O2•-) biosensor based on direct electron
transfer of copper, zinc-superoxide dismutase (Cu, Zn-SOD) at zinc oxide nanodisks surface …

The reaction mechanism for the disproportionation of the toxic superoxide radical to
molecular oxygen and hydrogen peroxide by the nickel-dependent superoxide dismutase …