Hydrogen atom transfer from a metal hydride (MHAT) has emerged as a powerful, if
puzzling, technique in chemical synthesis. In catalytic MHAT reactions, earth-abundant …

Cofactor-mimetic aerobic oxidation has conceptually merged with catalysis of syngas
reactions to form a wide range of Markovnikov-selective olefin radical …

The value of catalytic dehydrogenation of aliphatics (CDA) in organic synthesis has
remained largely underexplored. Known homogeneous CDA systems often require the use …

We report here a mechanistically distinct tactic to carry E2-type eliminations on alkyl halides.
This strategy exploits the interplay of α-aminoalkyl radical-mediated halogen-atom transfer …

Conspectus Mimicking photosynthesis and producing solar fuels is an appealing way to
store the huge amount of renewable energy from the sun in a durable and sustainable way …

[Co (bapbpy) Cl]+(bapbpy: 6, 6′-bis (2-aminopyridyl)-2, 2′-bipyridine) is a polypyridyl
cobalt (II) complex bearing both a redox-active bipyridine ligand and pendant proton relays …

Semiconductor/metal complex hybrids are promising photocatalysts for CO2 reduction. A
comprehensive mechanism investigation on charge dynamics was carried out for a hybrid g …

The positional isomerization of C═ C double bonds is a powerful strategy for the
interconversion of alkene regioisomers. However, existing methods provide access to …

The dehydrogenation of unactivated alkanes is an important transformation both in industrial
and biological systems. Recent efforts towards this reaction have revolved around high …

We report a general, intramolecular cycloisomerization of unactivated olefins with pendant
nucleophiles. The reaction proceeds under mild conditions and tolerates ethers, esters …