Practical chemical kinetics in solution

OA El Seoud, WJ Baader… - Encyclopedia of physical …, 2016 - Wiley Online Library
Most of the information about reaction mechanism comes from chemical kinetics. This
chapter first summarizes some of the basic terms related to the kinetic study of chemical …

Organocatalyzed living radical polymerization via in situ halogen exchange of alkyl bromides to alkyl iodides

L Xiao, K Sakakibara, Y Tsujii, A Goto - Macromolecules, 2017 - ACS Publications
Halogen exchange of alkyl bromide (R–Br) with sodium iodide (NaI) was used for the
transformation of R–Br to alkyl iodide (R–I) in situ in organocatalyzed living radical …

Diverse cation-promoted reactivity of iridium carbonyl pincer-crown ether complexes

J Grajeda, MR Kita, LC Gregor, PS White… - …, 2016 - ACS Publications
Several new iridium (I) and iridium (III) carbonyl complexes supported by aminophosphinite
pincer ligands have been prepared and characterized. A surprising diversity of reaction …

Bromoalkyl ATRP initiator activation by inorganic salts: experiments and computations

J Wang, J Han, H Peng, X Tang, J Zhu, RZ Liao… - Polymer …, 2019 - pubs.rsc.org
Ethyl α-bromophenylacetate (EBrPA) is able to initiate the bulk radical polymerisation of
methyl methacrylate (MMA) under thermal conditions (90° C) in the presence of a variety of …

LED-induced controlled radical polymerization with an in situ bromine–iodine transformation and block polymerization combined with ring-opening polymerization …

F Li, W Yang, M Li, L Lei - Polymer Chemistry, 2019 - pubs.rsc.org
A simple white light-emitting diode (LED) induced controlled radical polymerization (CRP)
with an in situ bromine–iodine transformation was successfully conducted via …

HMDS/KI a simple, a cheap and efficient catalyst for the one-pot synthesis of N-functionalized pyrimidines

AEE Mansouri, M Zahouily, HB Lazrek - Synthetic Communications, 2019 - Taylor & Francis
The syntheses of N-Alkylpyrimidine derivatives by reacting pyrimidin-2, 4-diones with
appropriate alkyl halide under microwave irradiation at 400 W were compared to the …

Conductimetric titrations: A predict− observe− explain activity for general chemistry

KC Smith, E Edionwe, B Michel - Journal of chemical education, 2010 - ACS Publications
A predict− observe− explain framework is used to explore conductimetric titrations of a
hydrochloric acid− sodium hydroxide (strong acid− strong base) and an acetic acid− sodium …

Organometallic elaboration as a strategy for tuning the supramolecular characteristics of aza-crown ethers

JB Smith, AM Camp, AH Farquhar, SH Kerr… - …, 2019 - ACS Publications
Outfitting an aza-crown ether with an organotransition-metal pendant provides a mechanism
for tuning its supramolecular properties. The binding affinity can be tuned by more than 2 …

Monocarbonyl analogs of curcumin based on the pseudopelletierine scaffold: synthesis and anti-inflammatory activity

D Pawelski, A Walewska, S Ksiezak… - International Journal of …, 2021 - mdpi.com
Curcumin (CUR) is a natural compound that exhibits anti-inflammatory, anti-bacterial, and
other biological properties. However, its application as an effective drug is problematic due …

A benchmark study of kinetic isotope effects and barrier heights for the Finkelstein reaction

S Zaczek, F Gelman… - The Journal of Physical …, 2017 - ACS Publications
Herein, we present a combined (experimental and computational) study of the Finkelstein
reaction in condensed phase, where bromine is substituted by iodine in 2 …