Catalytic strategies and mechanism analysis orbiting the center of critical intermediates in lignin depolymerization

C Zhang, X Shen, Y Jin, J Cheng, C Cai… - Chemical …, 2023 - ACS Publications
Lignin, as a precious resource given to mankind by nature with abundant functional aromatic
structures, has drawn much attention in the recent decade from academia to industry …

Electro-/photocatalytic alkene-derived radical cation chemistry: recent advances in synthetic applications

MJ Luo, Q Xiao, JH Li - Chemical Society Reviews, 2022 - pubs.rsc.org
Alkene-derived radical cations are versatile reactive intermediates and have been widely
applied in the construction of complex functionalized molecules and cyclic systems for …

[HTML][HTML] Recent advances in visible light-activated radical coupling reactions triggered by (i) ruthenium,(ii) iridium and (iii) organic photoredox agents

JD Bell, JA Murphy - Chemical Society Reviews, 2021 - pubs.rsc.org
Photoredox chemistry with organic or transition metal agents has been reviewed in earlier
years, but such is the pace of progress that we will overlap very little with earlier …

Photochemical and electrochemical applications of proton-coupled electron transfer in organic synthesis

PRD Murray, JH Cox, ND Chiappini, CB Roos… - Chemical …, 2021 - ACS Publications
We present here a review of the photochemical and electrochemical applications of multi-
site proton-coupled electron transfer (MS-PCET) in organic synthesis. MS-PCETs are redox …

Anti-Markovnikov intermolecular hydroamination of alkenes and alkynes: a mechanistic view

J Escorihuela, A Lledós, G Ujaque - Chemical Reviews, 2023 - ACS Publications
Hydroamination, the addition of an N–H bond across a C–C multiple bond, is a reaction with
a great synthetic potential. Important advances have been made in the last decades …

Photoredox-enabled dearomative [2π+ 2σ] cycloaddition of phenols

S Dutta, D Lee, K Ozols, CG Daniliuc… - Journal of the …, 2024 - ACS Publications
Dearomative photocycloaddition of monocyclic arenes is an appealing strategy for
comprehending the concept of “escape from flatland”. This brings the replacement of readily …

Discovery and characterization of an acridine radical photoreductant

IA MacKenzie, L Wang, NPR Onuska, OF Williams… - Nature, 2020 - nature.com
Photoinduced electron transfer (PET) is a phenomenon whereby the absorption of light by a
chemical species provides an energetic driving force for an electron-transfer reaction,,–. This …

Mechanistic studies in photocatalysis

L Buzzetti, GEM Crisenza… - Angewandte Chemie …, 2019 - Wiley Online Library
The fast‐moving fields of photoredox and photocatalysis have recently provided fresh
opportunities to expand the potential of synthetic organic chemistry. Advances in light …

Visible‐light photocatalysis: does it make a difference in organic synthesis?

L Marzo, SK Pagire, O Reiser… - Angewandte Chemie …, 2018 - Wiley Online Library
Visible‐light photocatalysis has evolved over the last decade into a widely used method in
organic synthesis. Photocatalytic variants have been reported for many important …

The advent and development of organophotoredox catalysis

T Bortolato, S Cuadros, G Simionato… - Chemical …, 2022 - pubs.rsc.org
In the last decade, photoredox catalysis has unlocked unprecedented reactivities in
synthetic organic chemistry. Seminal advancements in the field have involved the use of well …