The area of catalysis of radical reactions has recently flourished. Various reaction conditions
have been discovered and explained in terms of catalytic cycles. These cycles rarely stand …

Cascade radical cyclization is an attractive synthetic method due to its high atom-and step-
economy to construct carbo-and heterocycles, which have wide applications in chemical …

Tertiary carbon radicals have notable utility for uniting complex carbon fragments with
concomitant formation of new quaternary carbons. This article explores the scope …

A metal‐and catalyst‐free thiyl‐radical‐mediated activation of alkanes is described.
Tetrafluoropyridinyl disulfide is used to perform thiolation of the C− H bonds under …

Otherwise sluggish or completely ineffective radical reductions of alkyl and aryl halides by N-
heterocyclic carbene boranes (NHC-boranes) are catalyzed by thiols. Reductions and …

The coupling of tertiary carbon radicals with alkene acceptors is an underdeveloped strategy
for uniting complex carbon fragments and forming new quaternary carbons. The scope and …

This Concept shows the flexibility and applicability of (Me3Si) 3SiH in several synthetic
transformations, such as radical reductions, consecutive radical reactions and …

Under dry, anaerobic conditions, TiO2 photocatalysis of carboxylic acid precursors resulted
in carbon–carbon bond-forming processes. High yields of dimers were obtained from TiO2 …

A pyridine-boryl radical promoted reductive coupling reaction of aldehydes with 1, 1-
diarylethylenes has been established via a combination of computational and experimental …

Center stage: Additions of nitrogen‐centered radicals to cyanamide compounds provided
the first radical synthesis of aromatic polycyclic guanidine derivatives (see scheme). Modular …