Oxycarbenes have emerged as useful intermediates in synthetic chemistry. Compared to the
widely studied oxycarbene metal complexes bearing Group 6 metals, the synthetic and …

In recent decades, the traceless nature of visible photons has been exploited for the
development of efficient synthetic strategies for the photoconversion of colourless …

Multifunctionalization from the interception of active intermediates is an attractive synthetic
strategy for the efficient construction of complex molecular scaffolds in an atom and step …

Insertion reactions that involve stabilized electrophilic metallocarbenes are of great
importance for installing α‐heteroatoms to carbonyl compounds. Nevertheless, the limited …

We describe the first catalytic generation of Fischer-type acyloxy Rh (II)-carbenes from
carboxylic acids and Rh (II)-carbynoids. This novel class of transient donor/acceptor Rh (II) …

Fischer-type carbene complexes are characterized by the presence of a π-donating group,
such as an alkoxy group on the carbene carbon. Despite the notable progress that has been …

Herein, we disclose a ligand-controlled, directing group-assisted strategy to facilitate NiH-
catalyzed hydroalkynylation of allyl amides at remote α-position adjacent to nitrogen and …

Acylsilanes are an important class of organosilicon compounds that have gained increased
attention recently. Their various reaction modes in particularly their ability to generate …

Owing to their versatile reactivities, acylsilanes have long been used in organic synthesis.
However, unprecedentedly wide applications of this type of compound have been witnessed …

A Rh (II)-catalyzed oxy-alkynylation of acceptor–acceptor carbenes using EBX reagents was
successfully developed. The key alkyne-transfer step is likely to occur through a tandem …