Ce-mediated molecular tailoring on gigantic polyoxometalate {Mo132} into half-closed {Ce11Mo96} for high proton conduction

XX Li, CH Li, MJ Hou, B Zhu, WC Chen, CY Sun… - Nature …, 2023 - nature.com
Precise synthesis of polyoxometalates (POMs) is important for the fundamental
understanding of the relationship between the structure and function of each building motif …

Photocatalytic aerobic oxidation of C(sp3)-H bonds

L Zhang, RH Li, XX Li, S Wang, J Liu, XX Hong… - Nature …, 2024 - nature.com
In modern industries, the aerobic oxidation of C (sp3)-H bonds to achieve the value-added
conversion of hydrocarbons requires high temperatures and pressures, which significantly …

The long-distance charge transfer process in ferrocene-based MOFs with FeO6 clusters boosts photocatalytic CO2 chemical fixation

H Zhang, S Si, G Zhai, Y Li, Y Liu, H Cheng… - Applied Catalysis B …, 2023 - Elsevier
Metal nodes and organic ligands are important structural units of MOFs, and their properties
can profoundly affect the photocatalytic activity. Herein, two ferrocene-based MOFs with FeO …

Coordination chemistry and magnetic properties of polynuclear metal clusters/cluster-based frameworks with tripodal alcohol ligands

W Lv, SD Han, XY Li, GM Wang - Coordination Chemistry Reviews, 2023 - Elsevier
Metal clusters with atomically accurate structures and nanoscale sizes featuring size-
dependent chemical/physical properties have attracted a wide range of research interest of …

Photocatalytic production of ethylene and propionic acid from plastic waste by titania-supported atomically dispersed Pd species

S Zhang, B Xia, Y Qu, L Jing, M Jaroniec, J Ran… - Science …, 2023 - science.org
Current chemical recycling of bulk synthetic plastic, polyethylene (PE), operates at high
temperature/pressure and yields a complex mixture of products. PE conversion under mild …

High-coordinated BiV/BiIV regulates photocatalytic selective activation of structural oxygen and self-generated H2O2 dominating an efficient synergistic sterilization

Q Lian, Z Liang, X Guan, Z Tang, R Zhang… - Applied Catalysis B …, 2023 - Elsevier
This study revealed that the high-coordinated Bi V/Bi IV regulates the photocatalytic
selective activation of structural oxygen (O lat/O ads) and self-generated H 2 O 2 assisted by …

Photocatalytic Coupling of CH4 and CO2 to Ethanol on Asymmetric Ce−O−Zn Sites

S Hao, Y Chen, C Peng, H Wang, Q Wen… - Advanced Functional …, 2024 - Wiley Online Library
Partial oxidation of methane (CH4) to value‐added products is significantly challenging due
to the highly inert chemical property of CH4 at ambient conditions and easy over‐oxidation …

All-catecholate-stabilized black titanium-oxo clusters for efficient photothermal conversion

J Hou, N Huang, D Acharya, Y Liu, J Zhu, J Teng… - Chemical …, 2024 - pubs.rsc.org
The controlled synthesis of titanium-oxo clusters (TOCs) completely stabilized by organic
dye ligands with high stability and superior light absorption remains a significant challenge …

Ce4+/Ce3+ Redox Effect-Promoted CdS/CeO2 Heterojunction Photocatalyst for the Atom Economic Synthesis of Imines under Visible Light

F Sun, J Song, H Wen, X Cao, F Zhao, J Qin… - Inorganic …, 2023 - ACS Publications
The employment of stoichiometric alcohols and amines for imine synthesis under mild and
green reaction conditions is still a challenge in the field. In this work, based on our research …

Ce Doping Boosts the Photocatalytic Activity of Ultrathin Bi2MoO6 Nanosheets for Toluene Selective Oxidation

TQ Zeng, BH Wang, S Tian, ZJ Bai… - Industrial & …, 2023 - ACS Publications
The generation of reactive oxygen species (ROS) from O2 is a critical step to boost the
performance of photocatalytic toluene oxidation. However, the production of ROS is greatly …