The design and synthesis of lanthanide clusters with novel topological connections and
desirable properties are attracting extensive attention. Researchers have obtained …

As one of the most prosperous classes of cluster-based materials reported to date, polyoxo-
titanium clusters (PTCs) have been closely related to many photo-activities that broadly …

Polyoxotitanate nanoparticles play a crucial role as anodes in photovoltaic cells, 1 and as
photocatalysts in processes such as the oxidation of organic compounds in polluted air and …

Through the labile coordination sites of a robust phosphonate‐stabilized titanium–oxo
cluster, 14 O‐donor ligands have been successfully introduced without changing the cluster …

Complex metal oxides, defined as metal oxide materials with multiple metals, phases or
including dopants, are used in a huge variety of modern applications ranging from …

By using ethylene glycol and monocarboxylic acid as surface ligands, a series of cyclic Ti‐
oxo clusters (CTOC) with permanent microporosity are successfully synthesized. With a …

Metal-doped polyoxotitanium cages (M-POTs) of the type [TixOy (OR) zMnXm](M= a main
group, transition metal or lanthanide; X= an anion such as a halide) can be regarded as …

To exploit the use of solar energy in photocatalysis, metal ion doping is one of the most
effective ways. At present, atomically precise heterometallic polyoxotitanium clusters …

Functional ligand-modified polyoxotitanate (L-POT) cages of the general type [TixOy (OR) z
(L) m](OR= alkoxide, L= functional ligand) can be regarded as molecular fragments of …

Building blocks with multiple components are promising for the synthesis of complex
molecular assemblies, but are rarely available. Herein, we report a modification procedure …