This Review compiles the evolution, mechanistic understanding, and more recent advances
in enantioselective Pd-catalyzed allylic substitution and decarboxylative and oxidative allylic …

Enantioselective allylic substitution is one of the most important and reliable reactions for the
synthesis of chiral building blocks. While various transition metal catalysts have been …

Comprehensive computational studies were carried out to explore the mechanisms of
enantioselective Cu/Pd and stereodivergent Cu/Ir dual-catalytic syntheses of α, α …

Sulfones are common, readily available reagents that have recently attracted attention as
versatile reagents for cross-coupling reactions. This Review summarizes advances in …

Asymmetric reactions that convert racemic mixtures into enantioenriched amines are of
significant importance due to the prevalence of amines in pharmaceuticals, with about 60 …

Bakuchiol is an emblematic meroterpene class of natural product extracted from Psoralea
corylifolia. It has been reported to possess a broad range of biological and pharmacological …

The first molybdenum-catalyzed highly regio-and enantioselective allylic amination of both
aryl-and alkyl-substituted branched allylic carbonates has been developed. A wide variety of …

A modular and practical approach has been developed for the stereoselective formation of
elaborate allylic alcohols through a three-component reaction (3CR) between vinyl cyclic …

In recent years, the use of organosulfones as a new class of cross‐coupling partner in
transition‐metal catalyzed reactions has undergone significant advancement. In this …

An efficient palladium-catalyzed sulfonylative coupling for the synthesis of benzyl (allyl)
sulfones from sulfonyl hydrazides and carbonates was developed. The novel methodology …