Frustrated Lewis pair chemistry: development and perspectives

DW Stephan, G Erker - Angewandte Chemie International …, 2015 - Wiley Online Library
Abstract Frustrated Lewis pairs (FLPs) are combinations of Lewis acids and Lewis bases in
solution that are deterred from strong adduct formation by steric and/or electronic factors …

A unified survey of Si–H and H–H bond activation catalysed by electron-deficient boranes

M Oestreich, J Hermeke, J Mohr - Chemical Society Reviews, 2015 - pubs.rsc.org
The bond activation chemistry of B (C6F5) 3 and related electron-deficient boranes is
currently experiencing a renaissance due to the fascinating development of frustrated Lewis …

Frustrated lewis pairs

DW Stephan - Journal of the American Chemical Society, 2015 - ACS Publications
The articulation of the notion of “frustrated Lewis pairs”(FLPs), which emerged from the
discovery that H2 can be reversibly activated by combinations of sterically encumbered …

Incorporation of chiral frustrated Lewis pair into metal–organic framework with tailored microenvironment for heterogeneous enantio-and chemoselective …

Y Zhang, Y Jiang, A Nafady, Z Tang… - ACS Central …, 2023 - ACS Publications
The development of efficient heterogeneous catalysts with multiselectivity (eg, enantio-and
chemoselectivity) has long been sought after but with limited progress being made so far. To …

Chemie frustrierter Lewis‐Paare: Entwicklung und Perspektiven

DW Stephan, G Erker - Angewandte Chemie, 2015 - Wiley Online Library
Abstract Der Begriff “frustrierte Lewis‐Paare”(FLPs) bezeichnet Kombinationen von Lewis‐
Säuren und Lewis‐Basen in Lösung, die aufgrund sterischer oder elektronischer Faktoren …

“Frustrated Lewis pair” hydrogenations

DW Stephan - Organic & biomolecular chemistry, 2012 - pubs.rsc.org
This perspective article discusses developments of metal-free hydrogenation catalysts
derived from “frustrated Lewis pair”(FLP) systems. The range of catalysts uncovered and the …

Activation of hydrogen and hydrogenation catalysis by a borenium cation

JM Farrell, JA Hatnean… - Journal of the American …, 2012 - ACS Publications
Activation of Hydrogen and Hydrogenation Catalysis by a Borenium Cation | Journal of the
American Chemical Society ACS ACS Publications C&EN CAS Find my institution Log In …

Main group catalysed reduction of unsaturated bonds

K Revunova, GI Nikonov - Dalton Transactions, 2015 - pubs.rsc.org
This Perspective highlights the recent developments in the reduction of unsaturated
substrates catalysed by main group element compounds. Various activation modes are …

Chiral dienes as “ligands” for borane-catalyzed metal-free asymmetric hydrogenation of imines

Y Liu, H Du - Journal of the American Chemical Society, 2013 - ACS Publications
This paper describes a highly enantioselective metal-free hydrogenation of imines using
chiral dienes as “ligands” for the generation of catalysts with HB (C6F5) 2 by hydroboration …

A frustrated Lewis pair catalyzed asymmetric transfer hydrogenation of imines using ammonia borane

S Li, G Li, W Meng, H Du - Journal of the American Chemical …, 2016 - ACS Publications
Inspired by the zwitterion species generated from the splitting of H2 by frustrated Lewis
pairs, we put forward a novel frustrated Lewis pair by the combination of Hδ-and Hδ+ …