Photoactive copper complexes: properties and applications

J Beaudelot, S Oger, S Perusko, TA Phan… - Chemical …, 2022 - ACS Publications
Photocatalyzed and photosensitized chemical processes have seen growing interest
recently and have become among the most active areas of chemical research, notably due …

Photoactive Metal-to-Ligand Charge Transfer Excited States in 3d6 Complexes with Cr0, MnI, FeII, and CoIII

N Sinha, OS Wenger - Journal of the American Chemical Society, 2023 - ACS Publications
Many coordination complexes and organometallic compounds with the 4d6 and 5d6
valence electron configurations have outstanding photophysical and photochemical …

Exploiting the Marcus inverted region for first-row transition metal–based photoredox catalysis

AY Chan, A Ghosh, JT Yarranton, J Twilton, J Jin… - Science, 2023 - science.org
Second-and third-row transition metal complexes are widely employed in photocatalysis,
whereas earth-abundant first-row transition metals have found only limited use because of …

Luminescent first-row transition metal complexes

C Wegeberg, OS Wenger - Jacs Au, 2021 - ACS Publications
Precious and rare elements have traditionally dominated inorganic photophysics and
photochemistry, but now we are witnessing a paradigm shift toward cheaper and more …

Eliminating nonradiative decay in Cu (I) emitters:> 99% quantum efficiency and microsecond lifetime

R Hamze, JL Peltier, D Sylvinson, M Jung, J Cardenas… - Science, 2019 - science.org
Luminescent complexes of heavy metals such as iridium, platinum, and ruthenium play an
important role in photocatalysis and energy conversion applications as well as organic light …

Red light-based dual photoredox strategy resembling the Z-scheme of natural photosynthesis

F Glaser, OS Wenger - JACS Au, 2022 - ACS Publications
Photoredox catalysis typically relies on the use of single chromophores, whereas strategies,
in which two different light absorbers are combined, are rare. In photosystems I and II of …

3dd Excited States of Ni(II) Complexes Relevant to Photoredox Catalysis: Spectroscopic Identification and Mechanistic Implications

SI Ting, S Garakyaraghi, CM Taliaferro… - Journal of the …, 2020 - ACS Publications
Synthetic organic chemistry has seen major advances due to the merger of nickel and
photoredox catalysis. A growing number of Ni-photoredox reactions are proposed to involve …

Cu (I) complexes–Thermally activated delayed fluorescence. Photophysical approach and material design

R Czerwieniec, MJ Leitl, HHH Homeier… - Coordination Chemistry …, 2016 - Elsevier
Cu (I) complexes often show transitions of distinct metal-to-ligand charge transfer (MLCT)
character. This can lead to small energy separations between the lowest singlet S 1 and …

Heteroleptic diimine–diphosphine Cu (I) complexes as an alternative towards noble-metal based photosensitizers: Design strategies, photophysical properties and …

Y Zhang, M Schulz, M Wächtler, M Karnahl… - Coordination Chemistry …, 2018 - Elsevier
Photoactive Cu (I) complexes are considered as a promising alternative to traditional noble-
metal complexes that are mainly based on Ru (II) and Ir (III). Therefore, in recent years …

A low-spin Fe(iii) complex with 100-ps ligand-to-metal charge transfer photoluminescence

P Chábera, Y Liu, O Prakash, E Thyrhaug, AE Nahhas… - Nature, 2017 - nature.com
Transition-metal complexes are used as photosensitizers, in light-emitting diodes, for
biosensing and in photocatalysis. A key feature in these applications is excitation from the …