Photoactive copper complexes: properties and applications
J Beaudelot, S Oger, S Perusko, TA Phan… - Chemical …, 2022 - ACS Publications
Photocatalyzed and photosensitized chemical processes have seen growing interest
recently and have become among the most active areas of chemical research, notably due …
recently and have become among the most active areas of chemical research, notably due …
Photoactive Metal-to-Ligand Charge Transfer Excited States in 3d6 Complexes with Cr0, MnI, FeII, and CoIII
Many coordination complexes and organometallic compounds with the 4d6 and 5d6
valence electron configurations have outstanding photophysical and photochemical …
valence electron configurations have outstanding photophysical and photochemical …
Exploiting the Marcus inverted region for first-row transition metal–based photoredox catalysis
Second-and third-row transition metal complexes are widely employed in photocatalysis,
whereas earth-abundant first-row transition metals have found only limited use because of …
whereas earth-abundant first-row transition metals have found only limited use because of …
Luminescent first-row transition metal complexes
C Wegeberg, OS Wenger - Jacs Au, 2021 - ACS Publications
Precious and rare elements have traditionally dominated inorganic photophysics and
photochemistry, but now we are witnessing a paradigm shift toward cheaper and more …
photochemistry, but now we are witnessing a paradigm shift toward cheaper and more …
Eliminating nonradiative decay in Cu (I) emitters:> 99% quantum efficiency and microsecond lifetime
Luminescent complexes of heavy metals such as iridium, platinum, and ruthenium play an
important role in photocatalysis and energy conversion applications as well as organic light …
important role in photocatalysis and energy conversion applications as well as organic light …
Red light-based dual photoredox strategy resembling the Z-scheme of natural photosynthesis
Photoredox catalysis typically relies on the use of single chromophores, whereas strategies,
in which two different light absorbers are combined, are rare. In photosystems I and II of …
in which two different light absorbers are combined, are rare. In photosystems I and II of …
3dd Excited States of Ni(II) Complexes Relevant to Photoredox Catalysis: Spectroscopic Identification and Mechanistic Implications
SI Ting, S Garakyaraghi, CM Taliaferro… - Journal of the …, 2020 - ACS Publications
Synthetic organic chemistry has seen major advances due to the merger of nickel and
photoredox catalysis. A growing number of Ni-photoredox reactions are proposed to involve …
photoredox catalysis. A growing number of Ni-photoredox reactions are proposed to involve …
Cu (I) complexes–Thermally activated delayed fluorescence. Photophysical approach and material design
Cu (I) complexes often show transitions of distinct metal-to-ligand charge transfer (MLCT)
character. This can lead to small energy separations between the lowest singlet S 1 and …
character. This can lead to small energy separations between the lowest singlet S 1 and …
Heteroleptic diimine–diphosphine Cu (I) complexes as an alternative towards noble-metal based photosensitizers: Design strategies, photophysical properties and …
Y Zhang, M Schulz, M Wächtler, M Karnahl… - Coordination Chemistry …, 2018 - Elsevier
Photoactive Cu (I) complexes are considered as a promising alternative to traditional noble-
metal complexes that are mainly based on Ru (II) and Ir (III). Therefore, in recent years …
metal complexes that are mainly based on Ru (II) and Ir (III). Therefore, in recent years …
A low-spin Fe(iii) complex with 100-ps ligand-to-metal charge transfer photoluminescence
Transition-metal complexes are used as photosensitizers, in light-emitting diodes, for
biosensing and in photocatalysis. A key feature in these applications is excitation from the …
biosensing and in photocatalysis. A key feature in these applications is excitation from the …