Simulating the excited-state dynamics of polaritons with ab initio multiple spawning

B Rana, EG Hohenstein… - The Journal of Physical …, 2023 - ACS Publications
Over the past decade, there has been a growth of interest in polaritonic chemistry, where the
formation of hybrid light–matter states (polaritons) can alter the course of photochemical …

Photophysical transformations induced by chemical substitution to salicylaldimines

CA Barboza, P Gawrys, M Banasiewicz… - Physical Chemistry …, 2020 - pubs.rsc.org
A series of different electron-deficient aromatic substituents were used to investigate the role
of the electron-acceptor strength on the photophysical properties of salicylaldimine …

Ultrafast internal conversion and photochromism in gas-phase salicylideneaniline

MC Silfies, A Mehmood, G Kowzan… - The Journal of …, 2023 - pubs.aip.org
Salicylideneaniline (SA) is an archetypal system for excited-state intramolecular proton
transfer (ESIPT) in non-planar systems. Multiple channels for relaxation involving both the …

Impact of molecular arrangement and torsional motion on the fluorescence of salophen and its metal complexes

T Khan, A Datta - The Journal of Physical Chemistry C, 2017 - ACS Publications
Salophen is a weakly emissive molecule with a flexible structure. The decrease in the
flexibility of the molecule, which can be achieved by chemical or physical means, causes a …

Effect of nonplanarity on excited-state proton transfer and internal conversion in salicylideneaniline

S Pijeau, D Foster, EG Hohenstein - The Journal of Physical …, 2018 - ACS Publications
Salicylideneaniline (SA) is a prototype for excited-state intramolecular proton transfer
(ESIPT) reactions in nonplanar molecules. It is generally understood that the dominant …

Wavelength-dependent photochemistry of a salicylimine derivative studied with cryogenic and ultrafast spectroscopy approaches

K Artmann, CH Pollok, C Merten… - Physical Chemistry …, 2022 - pubs.rsc.org
Salicylimines are versatile compounds in which an excited-state intramolecular proton
transfer and torsional motions may set in upon photoexcitation. Here, we study N-(α …

Light induced reactions in cryogenic matrices (highlights 2015–2016)

R Fausto, T Nikitin, A Gómez-Zavaglia - 2017 - books.rsc.org
This chapter reviews investigations on light induced reactions in cryogenic matrices that
were reported in 2015 and 2016. Conformational isomerizations and tautomerizations as …

Polymorphism and conformational equilibrium of nitro-acetophenone in solid state and under matrix conditions

Ł Hetmańczyk, P Szklarz, A Kwocz, M Wierzejewska… - Molecules, 2021 - mdpi.com
Conformational and polymorphic states in the nitro-derivative of o-hydroxy acetophenone
have been studied by experimental and theoretical methods. The potential energy curves for …

UV-induced –OCH3 rotamerization in a matrix-isolated methoxy-substituted ortho-hydroxyaryl Schiff base

İ Sıdır, YG Sıdır, S Gobi, H Berber, GO Ildiz… - Photochemical & …, 2022 - Springer
A new methoxy-substituted ortho-hydroxyaryl Schiff base, 4-(3-methoxy-2-
hydroxybenzylidene-amino) phenol was synthesized from 4-aminophenol and 2-hydroxy-3 …

The molecules of colour

J Sérgio Seixas de Melo - 2017 - books.rsc.org
Indigo, alizarin, mauveine, brazilin and brazilein (the latter two being major colour
constituents of Brazilwood) are molecules that have had a strong impact in our civilization …