Towards chemistry at absolute zero

BR Heazlewood, TP Softley - Nature Reviews Chemistry, 2021 - nature.com
The prospect of cooling matter down to temperatures that are close to absolute zero raises
intriguing questions about how chemical reactivity changes under these extreme conditions …

Recent advances in quantum theory on ro-vibrationally inelastic scattering

D Yang, H Guo, D Xie - Physical Chemistry Chemical Physics, 2023 - pubs.rsc.org
Molecular collisions are of fundamental importance in understanding intermolecular
interaction and dynamics. Its importance is accentuated in cold and ultra-cold collisions …

Quantum state–resolved molecular dipolar collisions over four decades of energy

G Tang, M Besemer, S Kuijpers, GC Groenenboom… - Science, 2023 - science.org
Collisions between cold polar molecules represent a fascinating research frontier but have
proven hard to probe experimentally. We report measurements of inelastic cross sections for …

Stereodynamical control of cold collisions of polyatomic molecules with atoms

D Yang, D Xie, H Guo - The Journal of Physical Chemistry Letters, 2022 - ACS Publications
Scattering between atomic and/or molecular species can be controlled by manipulating the
orientation or alignment of the collision partners. Such stereodynamics is particularly …

Full-Dimensional Potential Energy Surface for Ro-vibrationally Inelastic Scattering between H2 Molecules

J Zuo, JFE Croft, Q Yao, N Balakrishnan… - Journal of Chemical …, 2021 - ACS Publications
We report a new full-dimensional potential energy surface (PES) for the inelastic scattering
between ro-vibrationally excited H2 molecules. The new PES is based on 39,462 multi …

[HTML][HTML] Energy transfer between vibrationally excited carbon monoxide based on a highly accurate six-dimensional potential energy surface

J Chen, J Li, JM Bowman, H Guo - The Journal of Chemical Physics, 2020 - pubs.aip.org
Energy transfer between vibrational modes can be quite facile, and it has been proposed as
the dominant mechanism for energy pooling in extreme environments such as nonthermal …

Cold collisions of hot molecules

CA Perera, C Amarasinghe, H Guo… - Physical Chemistry …, 2023 - pubs.rsc.org
In this Perspective, we review our recent work on rotationally inelastic collisions of highly
vibrationally excited NO molecules prepared in single rotational and parity levels at v= 10 …

Differential Cross Sections for Pair-Correlated Rotational Energy Transfer in NO(A2Σ+) + N2, CO, and O2: Signatures of Quenching Dynamics

TFM Luxford, TR Sharples, M Fournier… - The Journal of …, 2023 - ACS Publications
A crossed molecular beam, velocity-map ion-imaging apparatus has been used to
determine differential cross sections (DCSs), as a function of collider final internal energy, for …

Mapping partial wave dynamics in scattering resonances by rotational de-excitation collisions

T de Jongh, Q Shuai, GL Abma, S Kuijpers… - Nature Chemistry, 2022 - nature.com
One of the most important parameters in a collision is the 'miss distance'or impact parameter,
which in quantum mechanics is described by quantized partial waves. Usually, the collision …

High-resolution imaging of C+ He collisions using Zeeman deceleration and vacuum-ultraviolet detection

V Plomp, XD Wang, F Lique, J Kłos… - The Journal of …, 2021 - ACS Publications
High-resolution measurements of angular scattering distributions provide a sensitive test for
theoretical descriptions of collision processes. Crossed beam experiments employing a …