Towards chemistry at absolute zero
BR Heazlewood, TP Softley - Nature Reviews Chemistry, 2021 - nature.com
The prospect of cooling matter down to temperatures that are close to absolute zero raises
intriguing questions about how chemical reactivity changes under these extreme conditions …
intriguing questions about how chemical reactivity changes under these extreme conditions …
Recent advances in quantum theory on ro-vibrationally inelastic scattering
D Yang, H Guo, D Xie - Physical Chemistry Chemical Physics, 2023 - pubs.rsc.org
Molecular collisions are of fundamental importance in understanding intermolecular
interaction and dynamics. Its importance is accentuated in cold and ultra-cold collisions …
interaction and dynamics. Its importance is accentuated in cold and ultra-cold collisions …
Quantum state–resolved molecular dipolar collisions over four decades of energy
Collisions between cold polar molecules represent a fascinating research frontier but have
proven hard to probe experimentally. We report measurements of inelastic cross sections for …
proven hard to probe experimentally. We report measurements of inelastic cross sections for …
Stereodynamical control of cold collisions of polyatomic molecules with atoms
D Yang, D Xie, H Guo - The Journal of Physical Chemistry Letters, 2022 - ACS Publications
Scattering between atomic and/or molecular species can be controlled by manipulating the
orientation or alignment of the collision partners. Such stereodynamics is particularly …
orientation or alignment of the collision partners. Such stereodynamics is particularly …
Full-Dimensional Potential Energy Surface for Ro-vibrationally Inelastic Scattering between H2 Molecules
J Zuo, JFE Croft, Q Yao, N Balakrishnan… - Journal of Chemical …, 2021 - ACS Publications
We report a new full-dimensional potential energy surface (PES) for the inelastic scattering
between ro-vibrationally excited H2 molecules. The new PES is based on 39,462 multi …
between ro-vibrationally excited H2 molecules. The new PES is based on 39,462 multi …
[HTML][HTML] Energy transfer between vibrationally excited carbon monoxide based on a highly accurate six-dimensional potential energy surface
Energy transfer between vibrational modes can be quite facile, and it has been proposed as
the dominant mechanism for energy pooling in extreme environments such as nonthermal …
the dominant mechanism for energy pooling in extreme environments such as nonthermal …
Cold collisions of hot molecules
In this Perspective, we review our recent work on rotationally inelastic collisions of highly
vibrationally excited NO molecules prepared in single rotational and parity levels at v= 10 …
vibrationally excited NO molecules prepared in single rotational and parity levels at v= 10 …
Differential Cross Sections for Pair-Correlated Rotational Energy Transfer in NO(A2Σ+) + N2, CO, and O2: Signatures of Quenching Dynamics
TFM Luxford, TR Sharples, M Fournier… - The Journal of …, 2023 - ACS Publications
A crossed molecular beam, velocity-map ion-imaging apparatus has been used to
determine differential cross sections (DCSs), as a function of collider final internal energy, for …
determine differential cross sections (DCSs), as a function of collider final internal energy, for …
Mapping partial wave dynamics in scattering resonances by rotational de-excitation collisions
One of the most important parameters in a collision is the 'miss distance'or impact parameter,
which in quantum mechanics is described by quantized partial waves. Usually, the collision …
which in quantum mechanics is described by quantized partial waves. Usually, the collision …
High-resolution imaging of C+ He collisions using Zeeman deceleration and vacuum-ultraviolet detection
High-resolution measurements of angular scattering distributions provide a sensitive test for
theoretical descriptions of collision processes. Crossed beam experiments employing a …
theoretical descriptions of collision processes. Crossed beam experiments employing a …