[HTML][HTML] Separation mechanism, selectivity enhancement strategies and advanced materials for mono-/multivalent ion-selective nanofiltration membrane

D Lu, Z Yao, L Jiao, M Waheed, Z Sun, L Zhang - Advanced Membranes, 2022 - Elsevier
Mono-/multivalent ion-selective separation has become a common requirement at the water-
energy nexus, including energy storage and conversion, water purification, and sustainable …

Measuring surface charge: Why experimental characterization and molecular modeling should be coupled

R Hartkamp, AL Biance, L Fu, JF Dufrêche… - Current opinion in …, 2018 - Elsevier
Surface charge controls many static and dynamic properties of soft matter and
micro/nanofluidic systems, but its unambiguous measurement forms a challenge. Standard …

Confined water's dielectric constant reduction is due to the surrounding low dielectric media and not to interfacial molecular ordering

JF Olivieri, JT Hynes, D Laage - The Journal of Physical Chemistry …, 2021 - ACS Publications
Liquid water confined within nanometer-sized channels exhibits a surprisingly low dielectric
constant along the direction orthogonal to the channel walls. This is typically assumed to …

Universal reduction in dielectric response of confined fluids

MH Motevaselian, NR Aluru - ACS nano, 2020 - ACS Publications
Dielectric permittivity is central to many biological and physiochemical systems, as it affects
the long-range electrostatic interactions. Similar to many fluid properties, confinement …

Effect of hydrogen bonds on the dielectric properties of interfacial water

S Varghese, SK Kannam, JS Hansen, SP Sathian - Langmuir, 2019 - ACS Publications
The dielectric constant for water is reduced under confinement. Although this phenomenon
is well known, the underlying physical mechanism for the reduction is still in debate. In this …

Dielectric properties of water in charged nanopores

TR Underwood, IC Bourg - The Journal of Physical Chemistry B, 2022 - ACS Publications
In this study, we examine the spectral dielectric properties of liquid water in charged
nanopores over a wide range of frequencies (0.3 GHz to 30 THz) and pore widths (0.3 to 5 …

Dielectric permittivity of CSH

SA Hamadouche, T Honorio, T Bore… - Cement and Concrete …, 2023 - Elsevier
As a porous hydrophilic phase, C–S–H is expected to exhibit a frequency-dependent
dielectric response. This C–S–H property remains unknown, despite the importance of …

[HTML][HTML] Freezing water at constant volume and under confinement

MJ Powell-Palm, B Rubinsky, W Sun - Communications Physics, 2020 - nature.com
Water expands upon freezing. What happens when water is cooled below 0° C in an
undeformable, constant-volume container? This is a fundamental question in materials …

Anomalously low dielectric constant of ordered interfacial water

C Qi, Z Zhu, C Wang, Y Zheng - The Journal of Physical Chemistry …, 2021 - ACS Publications
Despite considerable effort, the dielectric constant of interfacial water at solid surfaces is still
not fully understood, thus hindering our understanding of the ubiquitous physical …

Tuning the dielectric response of water in nanoconfinement through surface wettability

E Papadopoulou, J Zavadlav, R Podgornik… - ACS …, 2021 - ACS Publications
The tunable polarity of water can be exploited in emerging technologies including catalysis,
gas storage, and green chemistry. Recent experimental and theoretical studies have shown …