Molecular firefighting—how modern phosphorus chemistry can help solve the challenge of flame retardancy

MM Velencoso, A Battig, JC Markwart… - Angewandte Chemie …, 2018 - Wiley Online Library
The ubiquity of polymeric materials in daily life comes with an increased fire risk, and
sustained research into efficient flame retardants is key to ensuring the safety of the …

[HTML][HTML] Atherton–Todd reaction: mechanism, scope and applications

SS Le Corre, M Berchel… - Beilstein journal of …, 2014 - beilstein-journals.org
Abstract Initially, the Atherton–Todd (AT) reaction was applied for the synthesis of
phosphoramidates by reacting dialkyl phosphite with a primary amine in the presence of …

Rethinking the pathway to sustainable fire retardants

J Feng, L Liu, Y Zhang, Q Wang, H Liang, H Wang… - …, 2023 - Wiley Online Library
Flame retardants are currently used in a wide range of industry sectors for saving lives and
property by mitigating fire hazards. The growing fire safety requirements for materials boost …

Eco-friendly flame retardant and smoke suppression coating containing boron compounds and phytic acids for nylon/cotton blend fabrics

J Liu, P Qi, D Meng, L Li, J Sun, H Li, X Gu… - Industrial Crops and …, 2022 - Elsevier
The flammability of nylon/cotton blend fabrics poses a great potential to cause fire hazard. A
bio-based boron contained flame retardant (PBN) in this work was obtained, and then was …

Flame-retardant and smoke-suppressant flexible polyurethane foams based on reactive phosphorus-containing polyol and expandable graphite

WH Rao, W Liao, H Wang, HB Zhao… - Journal of hazardous …, 2018 - Elsevier
In this manuscript, flame-retardant and smoke-suppressant flexible polyurethane foams
(FPUFs) were designed and synthesized based on novel liquid phosphorus-containing …

Fully bio-based coating for nylon/cotton blend fabrics with improved flame retardancy and smoke suppression properties

J Liu, P Qi, F Chen, J Zhang, H Li, X Gu, J Sun… - Progress in Organic …, 2023 - Elsevier
With the increasing requirements of eco-friendly flame retardant fabrics, fully bio-based
flame retardants have attracted more and more attention. In this work, a fully bio-based flame …

Recent developments in P (O/S)–N containing flame retardants

R Nazir, S Gaan - Journal of Applied Polymer Science, 2020 - Wiley Online Library
Synthesis of organophosphorus compounds containing nitrogen as heteroatom and its
application as a flame retardant (FR) have attracted much attention in the academic and …

[HTML][HTML] Preparation of flame-retardant polyurethane and its applications in the leather industry

S Lu, Y Feng, P Zhang, W Hong, Y Chen, H Fan, D Yu… - Polymers, 2021 - mdpi.com
As a novel polymer, polyurethane (PU) has been widely applied in leather, synthetic leather,
and textiles due to its excellent overall performance. Nevertheless, conventional PU is …

Ultra-low phosphorus loading to achieve the superior flame retardancy of epoxy resin

J Wang, C Ma, P Wang, S Qiu, W Cai, Y Hu - Polymer Degradation and …, 2018 - Elsevier
A novel phosphorus-containing compound (DOPO-THPO) is synthesized via the Atherton-
Todd-reaction between 9, 10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide (DOPO) …

Elucidating the thermal decomposition of dimethyl methylphosphonate by vacuum ultraviolet (VUV) photoionization: pathways to the PO radical, a key species in flame …

S Liang, P Hemberger, NM Neisius… - … A European Journal, 2015 - Wiley Online Library
The production of phosphoryl species (PO, PO2, HOPO) is believed to be of great
importance for efficient flame‐retardant action in the gas phase. We present a detailed …