Expanding the synthetic toolbox through metal–enzyme cascade reactions

S González-Granda, J Albarrán-Velo… - Chemical …, 2023 - ACS Publications
The combination of metal-, photo-, enzyme-, and/or organocatalysis provides multiple
synthetic solutions, especially when the creation of chiral centers is involved. Historically …

Construction of chemoenzymatic cascade reactions for bridging chemocatalysis and Biocatalysis: Principles, strategies and prospective

Y Liu, P Liu, S Gao, Z Wang, P Luan… - Chemical Engineering …, 2021 - Elsevier
Multi-step one-pot chemoenzymatic cascade reactions (mo-CECRs) bridging chemo-and
bio-catalysis can not only accomplish chemical transformations with minimized purification …

One-pot chemo-and photo-enzymatic linear cascade processes

JM Carceller, KS Arias, MJ Climent, S Iborra… - Chemical Society …, 2024 - pubs.rsc.org
The combination of chemo-and photocatalyses with biocatalysis, which couples the flexible
reactivity of the photo-and chemocatalysts with the highly selective and environmentally …

New reaction pathways by integrating chemo-and biocatalysis

L Bering, J Thompson, J Micklefield - Trends in Chemistry, 2022 - cell.com
The combination of chemo-and biocatalysis in one pot (integrated catalysis) is a powerful
approach to develop new routes towards important products under mild and environmentally …

Incorporation of metals and enzymes with porous imine molecule cages for highly efficient semiheterogeneous chemoenzymatic catalysis

S Gao, Y Liu, L Wang, Z Wang, P Liu, J Gao… - ACS …, 2021 - ACS Publications
Combining the advantages of homogeneous and heterogeneous catalysis is highly desired
but remains a challenging goal. Herein, we fabricated a semiheterogeneous metal–enzyme …

Palladium Nanoparticles Supported on Porous Silica Materials as Heterogeneous Catalysts of C− C Coupling and Cross‐Coupling Reactions

Á Mastalir, Á Molnár - ChemCatChem, 2023 - Wiley Online Library
Noble metal nanoparticles supported on porous silica materials represent an important class
of heterogeneous catalysts. Recently, a remarkable progress has been made concerning …

Enzyme-bimetallic hybrid catalyst for one-pot chemoenzymatic reactions

X Li, X Hu, Y Qiao, T Lu, Y Bai, J Xiong, X Li… - Chemical Engineering …, 2023 - Elsevier
To overcome the intrinsic incompatibility between enzyme and chemical catalysts in one-pot
chemoenzymatic cascade reactions, an enzyme-bimetallic hybrid catalyst was constructed …

Continuous artificial synthesis of glucose precursor using enzyme-immobilized microfluidic reactors

Y Zhu, Z Huang, Q Chen, Q Wu, X Huang, PK So… - Nature …, 2019 - nature.com
Food production in green crops is severely limited by low activity and poor specificity of D-
ribulose-1, 5-bisphosphate carboxylase/oxygenase (RuBisCO) in natural photosynthesis …

Mesoporous core–shell nanostructures bridging metal and biocatalyst for highly efficient cascade reactions

S Gao, Z Wang, L Ma, Y Liu, J Gao, Y Jiang - ACS Catalysis, 2019 - ACS Publications
Mesoporous core–shell structured nanocatalysts with a PdPt bimetallic core and enzyme-
immobilized polydopamine (PDA) shell were designed, in which the PDA shell worked as a …

γ‐Fe2O3@Cu3Al‐LDH/HEPES a novel heterogeneous amphoteric catalyst for synthesis of annulated pyrazolo[3,4‐d]pyrimidines

F Ghobakhloo, D Azarifar… - Applied …, 2022 - Wiley Online Library
An efficient synthetic method for the heterogenization of bifunctional zwitterionic HEPES
catalyst on LDH modified γ‐Fe2O3 magnetic nanoparticles (MNPs) was developed to create …