Aromatics and cyclic molecules in molecular clouds: A new dimension of interstellar organic chemistry

MC McCarthy, BA McGuire - The Journal of Physical Chemistry A, 2021 - ACS Publications
Astrochemistry lies at the nexus of astronomy, chemistry, and molecular physics. On the
basis of precise laboratory data, a rich collection of more than 200 familiar and exotic …

Detection of two interstellar polycyclic aromatic hydrocarbons via spectral matched filtering

BA McGuire, RA Loomis, AM Burkhardt, KLK Lee… - Science, 2021 - science.org
Unidentified infrared emission bands are ubiquitous in many astronomical sources. These
bands are widely, if not unanimously, attributed to collective emissions from polycyclic …

Discovery of the pure polycyclic aromatic hydrocarbon indene (c-C9H8) with GOTHAM observations of TMC-1

AM Burkhardt, KLK Lee, PB Changala… - The Astrophysical …, 2021 - iopscience.iop.org
Polycyclic aromatic hydrocarbons (PAHs) have long been invoked in the study of interstellar
and protostellar sources, but the unambiguous identification of any individual PAH has …

2021 census of interstellar, circumstellar, extragalactic, protoplanetary disk, and exoplanetary molecules

BA McGuire - The Astrophysical Journal Supplement Series, 2022 - iopscience.iop.org
To date, 241 individual molecular species, composed of 19 different elements, have been
detected in the interstellar and circumstellar medium by astronomical observations. These …

Discovery of interstellar 2-cyanoindene (2-C9H7CN) in GOTHAM observations of TMC-1

ML Sita, PB Changala, C Xue… - The Astrophysical …, 2022 - iopscience.iop.org
We present laboratory rotational spectroscopy of five isomers of cyanoindene (2-, 4-, 5-, 6-,
and 7-cyanoindene) using a cavity Fourier transform microwave spectrometer operating …

Interstellar detection of 2-cyanocyclopentadiene, C5H5CN, a second five-membered ring toward TMC-1

KLK Lee, PB Changala, RA Loomis… - The Astrophysical …, 2021 - iopscience.iop.org
Using radio observations with the Green Bank Telescope, evidence has now been found for
a second five-membered ring in the dense cloud Taurus Molecular Cloud-1 (TMC-1). Based …

Overview of desorption parameters of volatile and complex organic molecules-A systematic dig through the experimental literature

NFW Ligterink, M Minissale - Astronomy & Astrophysics, 2023 - aanda.org
Context. Many molecules observed in the interstellar medium are thought to result from the
thermal desorption of ices. Parameters such as the desorption energy and pre-exponential …

Ubiquitous aromatic carbon chemistry at the earliest stages of star formation

AM Burkhardt, RA Loomis, CN Shingledecker… - Nature …, 2021 - nature.com
Abstract Benzonitrile (c-C6H5CN, where 'c'indicates a cyclic structure), a polar proxy for
benzene (c-C6H6), has the potential to serve as a highly convenient radio probe for …

The role of terahertz and far-IR spectroscopy in understanding the formation and evolution of interstellar prebiotic molecules

DV Mifsud, PA Hailey, A Traspas Muiña… - Frontiers in Astronomy …, 2021 - frontiersin.org
Stellar systems are often formed through the collapse of dense molecular clouds which, in
turn, return copious amounts of atomic and molecular material to the interstellar medium. An …

Aromatic cycles are widespread in cold clouds

M Agúndez, N Marcelino, B Tercero… - Astronomy & …, 2023 - aanda.org
We report the detection of large hydrocarbon cycles toward several cold dense clouds. We
observed four sources (L1495B, Lupus-1A, L483, and L1527) in the Q band (31− 50 GHz) …