The molecular processes of urea hydrolysis in relation to ammonia emissions from agriculture

JJ Sigurdarson, S Svane, H Karring - Reviews in Environmental Science …, 2018 - Springer
Ammonia emissions from the agricultural sector give rise to numerous environmental and
societal concerns and represent an economic challenge in crop farming, causing a loss of …

The structure-based reaction mechanism of urease, a nickel dependent enzyme: tale of a long debate

L Mazzei, F Musiani, S Ciurli - JBIC Journal of Biological Inorganic …, 2020 - Springer
This review is an attempt to retrace the chronicle that starts from the discovery of the role of
nickel as the essential metal ion in urease for the enzymatic catalysis of urea, a key step in …

Understanding the electro-catalytic oxidation mechanism of urea on nickel electrodes in alkaline medium

V Vedharathinam, GG Botte - Electrochimica Acta, 2012 - Elsevier
In this paper, the electrocatalytic behavior of urea oxidation on a nickel electrode in alkaline
medium was investigated using various electrochemical techniques: cyclic voltammetry …

Urea removal from aqueous solutions—a review

E Urbańczyk, M Sowa, W Simka - Journal of Applied Electrochemistry, 2016 - Springer
The abundance of urea in the natural environment is dictated by the fact that it is one of the
major products of mammalian protein metabolism. Due to the extensive use of urea in many …

[HTML][HTML] A critical review on current urea removal technologies from water: An approach for pollution prevention and resource recovery

D Weerakoon, B Bansal, LP Padhye… - Separation and …, 2023 - Elsevier
Urea is the key nitrogenous waste product generated in the urea cycle in ureotelic animals.
Apart from that, urea and its derivatives are manufactured on a large scale for various …

Nonredox nickel enzymes

MJ Maroney, S Ciurli - Chemical reviews, 2014 - ACS Publications
The importance of nickel enzymes, where nickel serves as an essential cofactor, in Archaea,
bacteria, plants, and primitive eukaryotes, is well documented. 1 Despite the fact that no …

Dissociation rates of urea in the presence of NiOOH catalyst: a DFT analysis

DA Daramola, D Singh, GG Botte - The Journal of Physical …, 2010 - ACS Publications
Single molecule reactions have been studied between nickel oxyhydroxide, urea, and the
hydroxide ion to understand the process of urea dissociation into ammonia, isocyanic acid …

Chemistry of Ni2+ in Urease: Sensing, Trafficking, and Catalysis

B Zambelli, F Musiani, S Benini… - Accounts of chemical …, 2011 - ACS Publications
Transition metals are both essential to enzymatic catalysis and limited in environmental
availability. These two biological facts have together driven organisms to evolve …

Interplay of metal ions and urease

EL Carter, N Flugga, JL Boer, SB Mulrooney… - Metallomics, 2009 - academic.oup.com
Urease, the first enzyme to be crystallized, contains a dinuclear nickel metallocenter that
catalyzes the decomposition of urea to produce ammonia, a reaction of great agricultural …

Insights into the role and structure of plant ureases

C Follmer - Phytochemistry, 2008 - Elsevier
The broad distribution of ureases in leguminous seeds, as well as the accumulation pattern
of the protein during seed maturation, are suggestive of an important physiological role for …