A review on DBU-mediated organic transformations

SK Boddu, N Ur Rehman, TK Mohanta… - … Chemistry Letters and …, 2022 - Taylor & Francis
Diazabicyclo [5.4. 0] undec-7-ene (DBU) has received a significant importance in organic
synthesis during recent years because of its interesting ability to catalyze organic reaction …

Catalytic asymmetric benzidine rearrangement.

CK De, F Pesciaioli, B List - Angewandte Chemie, 2013 - search.ebscohost.com
The [3, 3]-diaza Cope rearrangement is a powerful synthetic principle that can be utilized to
generate a CÀC bond at the expense of an NÀN bond. It forms the basis of important and …

[PDF][PDF] 1, 8-Diazabicyclo [54.0 ļundec-7-ene (DBU): A Versatile Reagent in Organic Synthesis

B Nand, G Khanna, A Chaudhary, A Lumb… - Current organic …, 2015 - researchgate.net
This review focuses on the catalytic activity of the organic bicyclic amidine base, 1, 8-
diazabicyclo [540] undec-7-ene (DBU). It is available commercially, cheap and a …

One-pot synthesis of 2-amino-3-cyanopyridine derivatives catalyzed by ytterbium perfluorooctanoate [Yb (PFO) 3]

J Tang, L Wang, Y Yao, L Zhang, W Wang - Tetrahedron letters, 2011 - Elsevier
A family of 2-amino-3-cyanopyridine derivatives are synthesized from aldehydes, ketones,
malononitrile, and ammonium acetate via one-pot reaction catalyzed by ytterbium …

Chiral Holmium Complex-Catalyzed Diels–Alder Reaction of Silyloxyvinylindoles: Stereoselective Synthesis of Hydrocarbazoles

S Harada, T Morikawa, A Nishida - Organic letters, 2013 - ACS Publications
The catalytic and asymmetric cycloaddition between 3-[1-(silyloxy) vinyl] indoles and
electron-deficient olefins gave substituted hydrocarbazoles in up to 99% yield and 94% ee …

Catalytic enantioselective total synthesis of the picrotoxane alkaloids (−)-dendrobine,(−)-mubironine B, and (−)-dendroxine

L Guo, W Frey, B Plietker - Organic letters, 2018 - ACS Publications
A concise enantioselective total synthesis of three sesquiterpenoid alkaloids—(−)-
dendrobine,(−)-mubironine B, and (−)-dendroxine—is presented, which highlights the state …

Chiral holmium complex-catalyzed synthesis of hydrocarbazole from siloxyvinylindole and its application to the enantioselective total synthesis of (−)-Minovincine

T Morikawa, S Harada, A Nishida - The Journal of Organic …, 2015 - ACS Publications
The catalytic and enantioselective total synthesis of (−)-minovincine has been
accomplished. The key highly substituted hydrocarbazole derivative was obtained by an …

Catalytic and Enantioselective Diels‐Alder Reaction of Siloxydienes

S Harada, A Nishida - Asian Journal of Organic Chemistry, 2019 - Wiley Online Library
Diels‐Alder reaction is one of the most well‐known named reactions in organic chemistry. It
involves a diene substrate and a dienophile substrate. Among dienes, siloxydiene is a …

[HTML][HTML] Total synthesis of carbazomycins A and B

S Wu, S Harada, T Morikawa… - Chemical and …, 2018 - jstage.jst.go.jp
Total syntheses of carbazomycins A and B were demonstrated using a ytterbium-catalyzed
Diels–Alder reaction with (silyloxyvinyl) indole as a diene. The densely substituted benzene …

Optically Active Helical Lanthanide Complexes: Storable Chiral Lewis Acidic Catalysts for Enantioselective Diels–Alder Reaction of Siloxydienes

S Harada, S Nakashima, S Sekino… - Chemistry–An Asian …, 2020 - Wiley Online Library
Lanthanide triflates and a series of hexadentate chiral ligand complexes were synthesized.
X‐ray‐quality crystals were obtained from mixtures of the lanthanide complexes, which were …