Ni-catalyzed C–S bond construction and cleavage

S Huang, M Wang, X Jiang - Chemical Society Reviews, 2022 - pubs.rsc.org
Sulfur-containing compounds have attracted considerable interest due to their wide-ranging
applications in pharmaceuticals, agriculture, natural products, and organic materials. The …

Contemporary synthetic strategies in organofluorine chemistry

R Britton, V Gouverneur, JH Lin, M Meanwell… - Nature Reviews …, 2021 - nature.com
Fluorinated molecules have a wide range of applications and are used as medicines,
agrochemicals and refrigerants and in smartphone liquid crystal displays, photovoltaic solar …

Late-stage difluoromethylation: concepts, developments and perspective

JBI Sap, CF Meyer, NJW Straathof… - Chemical Society …, 2021 - pubs.rsc.org
This review describes the recent advances made in difluoromethylation processes based on
X–CF2H bond formation where X is C (sp), C (sp2), C (sp3), O, N or S, a field of research …

Desulfonylation via radical process: recent developments in organic synthesis

XQ Chu, D Ge, YY Cui, ZL Shen, CJ Li - Chemical reviews, 2021 - ACS Publications
As the “chemical chameleon”, sulfonyl-containing compounds and their variants have been
merged with various types of reactions for the efficient construction of diverse molecular …

Beyond classical sulfone chemistry: metal-and photocatalytic approaches for C–S bond functionalization of sulfones

J Corpas, SH Kim-Lee, P Mauleón… - Chemical Society …, 2022 - pubs.rsc.org
The exceptional versatility of sulfones has been extensively exploited in organic synthesis
across several decades. Since the first demonstration in 2005 that sulfones can participate …

Transition-metal (Cu, Pd, Ni)-catalyzed difluoroalkylation via cross-coupling with difluoroalkyl halides

Z Feng, YL Xiao, X Zhang - Accounts of Chemical Research, 2018 - ACS Publications
Conspectus Difluoroalkylated compounds play a remarkably important role in life and
materials sciences because of the unique characteristics of the difluoromethylene (CF2) …

Recent Advances in Mn, Fe, Co, and Ni-Catalyzed Organic Reactions

LJ Li, Y He, Y Yang, J Guo, Z Lu, C Wang… - CCS …, 2024 - chinesechemsoc.org
This paper reviewed the recent research progress of organic reactions catalyzed by four
typical earth-abundant and 3d metal catalysts: Mn, Fe, Co, and Ni complexes and mainly …

Transition-metal mediated carbon–sulfur bond activation and transformations: an update

J Lou, Q Wang, P Wu, H Wang, YG Zhou… - Chemical Society …, 2020 - pubs.rsc.org
Carbon–sulfur bond cross-coupling has become more and more attractive as an alternative
protocol to establish carbon–carbon and carbon–heteroatom bonds. Diverse …

Where does the fluorine come from? A review on the challenges associated with the synthesis of organofluorine compounds

S Caron - Organic Process Research & Development, 2020 - ACS Publications
Fluorinated organic molecules are increasingly being prepared for a variety of applications,
including pharmaceutical products. However, the supply chain to access the necessary raw …

Direct synthesis of unprotected aryl C-glycosides by photoredox Ni-catalysed cross-coupling

C Zhang, SY Xu, H Zuo, X Zhang, QD Dang, D Niu - Nature Synthesis, 2023 - nature.com
Aryl C-glycosides are an important class of carbohydrate derivatives, with widespread
application in drug development, biochemistry and material sciences. However, their …