The debatable role of singlet oxygen in persulfate-based advanced oxidation processes

L Wang, K Xiao, H Zhao - Water Research, 2023 - Elsevier
Abstract Singlet oxygen (1 O 2) attracts much attention in persulfate-based advanced
oxidation processes (PS-AOPs), because of its wide pH tolerance and high selectivity …

Singlet oxygen: Properties, generation, detection, and environmental applications

Y Wang, Y Lin, S He, S Wu, C Yang - Journal of Hazardous Materials, 2023 - Elsevier
Abstract Singlet oxygen (1 O 2) is molecular oxygen in the excited state with high energy
and electrophilic property. It is widely found in nature, and its important role is gradually …

Water decontamination via nonradical process by nanoconfined Fenton-like catalysts

T Liu, S Xiao, N Li, J Chen, X Zhou, Y Qian… - Nature …, 2023 - nature.com
There is an urgent need to develop effective and sustainable solutions to reduce water
pollution. Heterogeneous Fenton-like catalysts are frequently used to eliminate …

CoN1O2 Single‐Atom Catalyst for Efficient Peroxymonosulfate Activation and Selective Cobalt(IV)=O Generation

X Li, X Wen, J Lang, Y Wei, J Miao, X Zhang… - Angewandte …, 2023 - Wiley Online Library
High‐valent metal‐oxo (HVMO) species are powerful non‐radical reactive species that
enhance advanced oxidation processes (AOPs) due to their long half‐lives and high …

Almost 100% electron transfer regime over Fe− Co dual-atom catalyst toward pollutants removal: Regulation of peroxymonosulfate adsorption mode

F Wang, Y Gao, H Fu, SS Liu, Y Wei, P Wang… - Applied Catalysis B …, 2023 - Elsevier
Fe− Co dual-atom catalyst (FeCo− DAC) with FeCo− N 6 moiety anchored in the carbon
skeleton is fabricated to achieve a nearly 100% electron-transfer process (ETP) for high …

Ultrahigh peroxymonosulfate utilization efficiency over CuO nanosheets via heterogeneous Cu (III) formation and preferential electron transfer during degradation of …

Y Wei, J Miao, J Ge, J Lang, C Yu… - Environmental …, 2022 - ACS Publications
In persulfate activation by copper-based catalysts, high-valent copper (Cu (III)) is an
overlooked reactive intermediate that contributes to efficient persulfate utilization and …

Review of characteristics, generation pathways and detection methods of singlet oxygen generated in advanced oxidation processes (AOPs)

ZH Xie, CS He, DN Pei, Y Dong, SR Yang… - Chemical Engineering …, 2023 - Elsevier
Advanced oxidation processes (AOPs) have been widely used in contaminants
decomposition to reduce their harm. Especially, the singlet oxygen (1 O 2)-mediated AOPs …

Non-radical activation of peracetic acid by powdered activated carbon for the degradation of sulfamethoxazole

Z Wang, Z Chen, Q Li, J Wang, L Cao… - Environmental …, 2023 - ACS Publications
Environmental-friendly and low-cost catalysts for peracetic acid (PAA) activation are vital to
promote their application for micropollutant degradation in water. In this study, powdered …

Generation and identification of 1O2 in catalysts/peroxymonosulfate systems for water purification

Q Fang, H Yang, S Ye, P Zhang, M Dai, X Hu, Y Gu… - Water Research, 2023 - Elsevier
Catalysts for peroxymonosulfate (PMS) activation are appealing in the purification of organic
wastewater. Singlet oxygen (1 O 2) is widely recognized as a crucial reactive species for …

Facilely tuning the first-shell coordination microenvironment in iron single-atom for Fenton-like chemistry toward highly efficient wastewater purification

Z Wu, B Huang, X Wang, CS He, Y Liu… - Environmental …, 2023 - ACS Publications
Precisely identifying the atomic structures in single-atom sites and establishing authentic
structure–activity relationships for single-atom catalyst (SAC) coordination are significant …