Reactions in single-molecule junctions

H Chen, C Jia, X Zhu, C Yang, X Guo… - Nature Reviews …, 2023 - nature.com
Developing new materials is a long-standing goal that extends across the fields of synthesis,
catalysis, nanotechnology and materials science. Transforming one compound or material …

Towards single molecule switches

JL Zhang, JQ Zhong, JD Lin, WP Hu, K Wu… - Chemical Society …, 2015 - pubs.rsc.org
The concept of using single molecules as key building blocks for logic gates, diodes and
transistors to perform basic functions of digital electronic devices at the molecular scale has …

Photoswitches: from molecules to materials

MM Russew, S Hecht - Advanced Materials, 2010 - Wiley Online Library
Small organic molecules, capable of undergoing efficient and reversible photochemical
reactions to switch them between (at least) two (meta) stable isomers associated with …

Remote-controlling chemical reactions by light: Towards chemistry with high spatio-temporal resolution

R Göstl, A Senf, S Hecht - Chemical Society Reviews, 2014 - pubs.rsc.org
The foundation of the chemical enterprise has always been the creation of new molecular
entities, such as pharmaceuticals or polymeric materials. Over the past decades, this …

Acylhydrazones as widely tunable photoswitches

DJ Van Dijken, P Kovaříček, SP Ihrig… - Journal of the American …, 2015 - ACS Publications
Molecular photoswitches have attracted much attention in biological and materials contexts.
Despite the fact that existing classes of these highly interesting functional molecules have …

Artificial light‐gated catalyst systems

RS Stoll, S Hecht - Angewandte Chemie International Edition, 2010 - Wiley Online Library
Having control over an entity or even an entire process is arguably the ultimate
demonstration of its understanding and it will enable its potential to be fully exploited. With …

Charge transport through molecular switches

SJ van der Molen, P Liljeroth - Journal of Physics: Condensed …, 2010 - iopscience.iop.org
We review the fascinating research on charge transport through switchable molecules. In the
past decade, detailed investigations have been performed on a great variety of molecular …

Controlling intramolecular hydrogen transfer in a porphycene molecule with single atoms or molecules located nearby

T Kumagai, F Hanke, S Gawinkowski, J Sharp… - Nature Chemistry, 2014 - nature.com
Although the local environment of a molecule can play an important role in its chemistry,
rarely has it been examined experimentally at the level of individual molecules. Here we …

Quantum chemical investigation of thermal cis-to-trans isomerization of azobenzene derivatives: substituent effects, solvent effects, and comparison to experimental …

J Dokic, M Gothe, J Wirth, MV Peters… - The Journal of …, 2009 - ACS Publications
Quantum chemical calculations of various azobenzene (AB) derivatives have been carried
out with the goal to describe the energetics and kinetics of their thermal cis→ trans …

Molecular factors controlling the isomerization of azobenzenes in the cavity of a flexible coordination cage

L Pesce, C Perego, AB Grommet, R Klajn… - Journal of the …, 2020 - ACS Publications
Photoswitchable molecules are employed for many applications, from the development of
active materials to the design of stimuli-responsive molecular systems and light-powered …