Polymerization within Nanoporous Anodized Alumina Oxide Templates (AAO): A Critical Survey

C Mijangos, J Martin - Polymers, 2023 - mdpi.com
In the last few years, the polymerization of monomers within the nanocavities of porous
materials has been thoroughly studied and developed, allowing for the synthesis of …

[PDF][PDF] The green chemistry paradigm in modern organic synthesis

SG Zlotin, KS Egorova, VP Ananikov… - RUSSIAN CHEMICAL …, 2023 - researchgate.net
After the appearance of the green chemistry concept, which was introduced in the chemistry
vocabulary in the early 1990s, its main statements have been continuously developed and …

Kinetic study of alkyl methacrylate polymerization in nanoporous confinement over a broad temperature range

Q Tian, H Zhao, SL Simon - Polymer, 2020 - Elsevier
The effect of nanoconfinement on the free radical polymerization of ethyl methacrylate (EMA)
and n-butyl-methacrylate (BMA) with di-tert-butyl peroxide (DtBP) initiator is investigated …

Direct laser writing to generate molds for polymer nanopillar replication

C Delaney, N Geoghegan, H Ibrahim… - ACS Applied Polymer …, 2020 - ACS Publications
Herein, we exploit direct laser writing as a means to fabricate negative masters for the
generation of polymeric nanopillars, via replica molding. Through the optimization of design …

[HTML][HTML] Synthetic strategy matters: The study of a different kind of PVP as micellar vehicles of metronidazole

R Bielas, P Maksym, M Tarnacka, A Minecka… - Journal of Molecular …, 2021 - Elsevier
Abstract Poly (1-vinyl-2-pyrrolidone)(Povidone, PVP) is one of the most interesting and
versatile synthetic polymers utilised in the pharmaceutical and cosmetic industries. Its large …

Kinetics of nanoconfined benzyl methacrylate radical polymerization

C Zhai, YP Koh, BD Vogt… - Journal of Polymer …, 2024 - Wiley Online Library
The effect of nanoconfinement on the kinetics of benzyl methacrylate radical polymerization
is investigated using differential scanning calorimetry. Controlled pore glass (CPG), ordered …

The unique role of pore wall nanostructurization in the intrachannel photo-ATRP for fine-tuning PMMA tacticity

P Maksym, R Bernat, K Koperwas… - Chemical …, 2022 - pubs.rsc.org
In this paper, efficient MMA photo O-ATRP protocols conducted inside nanoreactors varying
in nanostructured interfaces are reported for the first time. We showed that the microstructure …

Free radical nanocopolymerization in AAO porous materials: Kinetic, copolymer composition and monomer reactivity ratios

L León-Boigues, R Navarro, C Mijangos - Polymer, 2021 - Elsevier
Free radical (FR) polymerization in non-interconnected nanochannels of anodic aluminum
oxide templates (AAO) represents a suitable and less energetic method to prepare …

Hard confinement systems as effective nanoreactors for in situ photo-RAFT: towards control over molecular weight distribution and morphology

R Bernat, P Maksym, M Tarnacka, A Szelwicka… - Polymer …, 2021 - pubs.rsc.org
This work highlights the development of a robust and universal route towards gaining control
over macromolecule molecular weight, molecular weight distribution and, more importantly …

High pressure as a novel tool for the cationic ROP of γ-butyrolactone

R Bernat, P Maksym, M Tarnacka, K Malarz… - RSC …, 2021 - pubs.rsc.org
In this study, we report the acid-catalyzed and high pressure assisted ring-opening
polymerization (ROP) of γ-butyrolactone (GBL). The use of a dually-catalyzed approach …