Coordination polymers and metal–organic frameworks based on poly (pyrazole)-containing ligands

C Pettinari, A Tăbăcaru, S Galli - Coordination Chemistry Reviews, 2016 - Elsevier
In the past two decades, the vast classes of coordination polymers (CPs) and metal–organic
frameworks (MOFs) have received deep attention in both the academic and industrial …

Derisking the Cu-Mediated 18F-Fluorination of Heterocyclic Positron Emission Tomography Radioligands

NJ Taylor, E Emer, S Preshlock… - Journal of the …, 2017 - ACS Publications
Molecules labeled with fluorine-18 (18F) are used in positron emission tomography to
visualize, characterize and measure biological processes in the body. Despite recent …

Inverse coordination–An emerging new chemical concept. Oxygen and other chalcogens as coordination centers

I Haiduc - Coordination Chemistry Reviews, 2017 - Elsevier
Inverse coordination is the formation of metal complexes in which the arrangement of
acceptor and donor sites is opposite to that occurring in conventional coordination …

Antisymmetric exchange in triangular tricopper (II) complexes: correlation among structural, magnetic, and electron paramagnetic resonance parameters

S Ferrer, F Lloret, E Pardo, JM Clemente-Juan… - Inorganic …, 2012 - ACS Publications
Two new trinuclear copper (II) complexes,[Cu3 (μ3-OH)(daat)(Hdat) 2 (ClO4) 2 (H2O)
3](ClO4) 2· 2H2O (1) and [Cu3 (μ3-OH)(aaat) 3 (H2O) 3](ClO4) 2· 3H2O (2)(daat= 3, 5 …

Designing functional metal–organic frameworks by imparting a hexanuclear copper-based secondary building unit specific properties: structural correlation with …

S Bala, S Bhattacharya, A Goswami… - Crystal growth & …, 2014 - ACS Publications
In continuation of our research interest in pyrazole-based multifunctional metal organic
frameworks (MOFs), we report here three Cu (II) MOFs using pyrazole and various aromatic …

Anion− π interaction-directed assembly of polyoxometalate-based host–guest compounds and its contribution to photochromism

JZ Liao, XY Wu, JP Yong, HL Zhang… - Crystal Growth & …, 2015 - ACS Publications
Two rare copper-based host–guest crystalline compounds were synthesized with different
photoresponsive reversible visible light photochromism as a result of blending of …

An efficient mixed-valence copper pyrazolate catalyst for the conversion of carbon dioxide and epoxides into cyclic carbonates

JG Wang, Y Liu, CM Liu, JH Chen, G Yang - Dalton Transactions, 2023 - pubs.rsc.org
In this paper, a cyclic (CuIpz) 3· CH3CN (1) precursor and a mixed-valence pentanuclear
complex CuI3CuII2 (OH) pz6· CH3CN (2) have been synthesized and structurally …

Designing Multifunctional MOFs Using the Inorganic Motif [Cu33-OH)(μ-Pyz)] as an SBU and Their Properties

S Akhtar, S Bala, A De, KS Das, A Adhikary… - Crystal Growth & …, 2018 - ACS Publications
In a continuation of our interest in pyrazole-based multifunctional metal–organic frameworks
(MOFs), we report herein the construction of a series of Cu (II) MOFs using pyrazole and …

New Coordination Polymers and Porous Supramolecular Metal Organic Network Based on the Trinuclear Triangular Secondary Building Unit [Cu3 (μ3-OH)(μ-pz) 3] 2 …

C Di Nicola, F Garau, M Gazzano… - Crystal growth & …, 2012 - ACS Publications
The trinuclear triangular CuII complex [Cu3 (μ3-OH)(μ-pz) 3 (HCOO) 2 (Hpz) 2](Hpz=
pyrazole) reacts with 4, 4′-bipyridine (bpy) yielding a two-dimensional (2D) waved sheets …

Capped Nanojars: Synthesis, Solution and Solid-State Characterization, and Atmospheric CO2 Sequestration by Selective Binding of Carbonate

WA Al Isawi, M Zeller, G Mezei - Inorganic Chemistry, 2021 - ACS Publications
Nanojars are a class of supramolecular anion-incarcerating coordination complexes that self-
assemble from Cu2+ ions, pyrazole, and a strong base in the presence of highly hydrophilic …