Oxidation states in metallocenes: A key mechanistic component in cancer alleviation

R Das, DR Chatterjee, A Shard - Coordination Chemistry Reviews, 2024 - Elsevier
Metal complexes are widely employed in cancer treatment. The several tuning variables
provide peerless possibilities for drug development strategies. This results in a diverse …

Intermolecular and electrode-molecule bonding in a single dimer junction of naphthalenethiol as revealed by surface-enhanced Raman scattering combined with …

K Homma, S Kaneko, K Tsukagoshi… - Journal of the American …, 2023 - ACS Publications
Electron transport through noncovalent interaction is of fundamental and practical
importance in nanomaterials and nanodevices. Recent single-molecule studies employing …

Organometallics in molecular junctions: conductance, functions, and reactions

Y Tanaka - Dalton Transactions, 2024 - pubs.rsc.org
Molecular junctions, which involve sandwiching molecular structures between electrodes,
play a crucial role in molecular electronics. Recent advances in this field have revealed the …

Photooxidation driven formation of Fe-Au linked ferrocene-based single-molecule junctions

W Lee, L Li, M Camarasa-Gómez… - Nature …, 2024 - nature.com
Metal-metal contacts, though not yet widely realized, may provide exciting opportunities to
serve as tunable and functional interfaces in single-molecule devices. One of the simplest …

Cooperative Self-Assembly of Dimer Junctions Driven by π Stacking Leads to Conductance Enhancement

X Pan, E Montes, WY Rojas, B Lawson, H Vázquez… - Nano Letters, 2023 - ACS Publications
We demonstrate enhanced electronic transport through dimer molecular junctions, which
self-assemble between two gold electrodes in π–π stabilized binding configurations. Single …

Single-Molecule Conductance of Intramolecular Hydrogen Bonding in Histamine on Gold

X Pan, K Matthews, B Lawson… - The Journal of Physical …, 2023 - ACS Publications
We perform single-molecule conductance measurements and DFT calculations on
histamine, a biogenic amine that contains a flexible aliphatic linker and several nitrogen …

A new anchoring group to fabricate single-molecule junctions: diphenyl sulfide

Z Hu, Y Wang, L Liang, M Wang, B Xiao… - Journal of Materials …, 2024 - pubs.rsc.org
Diphenyl sulfide is connected with one or two thioanisoles, in a system initially prepared to
learn about the electronic charge transport through it. Unexpectedly, we observed a …

Resonant transport in a highly conducting single molecular junction via metal–metal covalent bond

B Pabi, Š Marek, A Pal, P Kumari, SJ Ray, A Thakur… - Nanoscale, 2023 - pubs.rsc.org
Achieving highly transmitting molecular junctions through resonant transport at low bias is
key to the next-generation low-power molecular devices. Although resonant transport in …

Atomically precise binding conformations of adenine and its variants on gold using single molecule conductance signatures

X Pan, C Qian, A Chow, L Wang… - The Journal of Chemical …, 2022 - pubs.aip.org
We demonstrate single molecule conductance as a sensitive and atomically precise probe
of binding configurations of adenine and its biologically relevant variants on gold. By …

Ionization of Decamethylmanganocene: Insights from the DFT-Assisted Laser Spectroscopy

S Ketkov, SY Tzeng, E Rychagova, WB Tzeng - Molecules, 2022 - mdpi.com
Metallocenes represent one of the most important classes of organometallics with wide
prospects for practical use in various fields of chemistry, materials science, molecular …