Single ion magnets from 3d to 5f: developments and strategies
M Feng, ML Tong - Chemistry–A European Journal, 2018 - Wiley Online Library
Abstract Single‐ion magnets (SIMs), exhibiting slow magnetization relaxation in the absence
of the magnetic field, originate from their single spin‐carrier centre. In pursuit of high …
of the magnetic field, originate from their single spin‐carrier centre. In pursuit of high …
Role of Coordination Number and Geometry in Controlling the Magnetic Anisotropy in FeII, CoII, and NiII Single‐Ion Magnets
Since the last decade, the focus in the area of single‐molecule magnets (SMMs) has been
shifting constructively towards the development of single‐ion magnets (SIMs) based on …
shifting constructively towards the development of single‐ion magnets (SIMs) based on …
A Pseudo‐Octahedral Cobalt (II) Complex with Bispyrazolylpyridine Ligands Acting as a Zero‐Field Single‐Molecule Magnet with Easy Axis Anisotropy
The homoleptic mononuclear compound [Co (bpp‐COOMe) 2](ClO4) 2 (1)(bpp‐COOMe=
methyl 2, 6‐di (pyrazol‐1‐yl) pyridine‐4‐carboxylate) crystallizes in the monoclinic C2/c …
methyl 2, 6‐di (pyrazol‐1‐yl) pyridine‐4‐carboxylate) crystallizes in the monoclinic C2/c …
Probing the axial distortion effect on the magnetic anisotropy of octahedral Co (II) complexes
Three mononuclear octahedral Co (II) complexes are reported,[Co (py) 4 (SCN) 2](1),[Co
(py) 4 (Cl) 2]· H2O (2), and [Co (py) 4 (Br) 2](3), that exhibit different distortions with …
(py) 4 (Cl) 2]· H2O (2), and [Co (py) 4 (Br) 2](3), that exhibit different distortions with …
Field-induced single-ion magnet behavior in a hydrogen-bonded supramolecular cobalt (II) complex
D Shao, SY She, LF Shen, X Yang, Z Tian - Polyhedron, 2022 - Elsevier
Hydrogen-bonded supramolecular frameworks remain highly interesting for the
development of novel porous materials. Herein a hydrogen-bonded supramolecular …
development of novel porous materials. Herein a hydrogen-bonded supramolecular …
Modulation of the magnetic anisotropy of octahedral cobalt (II) single-ion magnets by fine-tuning the axial coordination microenvironment
Y Wu, D Tian, J Ferrando-Soria, J Cano, L Yin… - Inorganic Chemistry …, 2019 - pubs.rsc.org
Two mononuclear cobalt (II) complexes, with the formulas [Co (2, 6-dfba) 2 (bpp) 2 (H2O) 2]
n (1) and [Co (2, 6-dfba) 2 (bpe) 2 (H2O) 2] n (2)(2, 6-Hdfba= 2, 6-difluorobenzoic acid, bpp …
n (1) and [Co (2, 6-dfba) 2 (bpe) 2 (H2O) 2] n (2)(2, 6-Hdfba= 2, 6-difluorobenzoic acid, bpp …
Analysis of Magnetic Anisotropy and the Role of Magnetic Dilution in Triggering Single‐Molecule Magnet (SMM) Behavior in a Family of CoIIYIII Dinuclear …
MA Palacios, J Nehrkorn, EA Suturina… - … A European Journal, 2017 - Wiley Online Library
Three new closely related CoIIYIII complexes of general formula [Co (μ‐L)(μ‐X) Y (NO3)
2](X−= NO3− 1, benzoate 2, or 9‐anthracenecarboxylato 3) have been prepared with the …
2](X−= NO3− 1, benzoate 2, or 9‐anthracenecarboxylato 3) have been prepared with the …
Field-assisted slow magnetic relaxation in a six-coordinate Co (II)–Co (III) complex with large negative anisotropy
The reaction of Co (CH3COO) 2· 4H2O with the Schiff base ligand LH4 derived from o-
vanillin and tris (hydroxymethyl) aminomethane produces the dinuclear mixed-valence …
vanillin and tris (hydroxymethyl) aminomethane produces the dinuclear mixed-valence …
Evidence of field induced slow magnetic relaxation in cis-[Co (hfac) 2 (H 2 O) 2] exhibiting tri-axial anisotropy with a negative axial component
We report a combined experimental characterization and theoretical modeling of the hexa-
coordinated high-spin Co (II) complex cis-[Co (hfac) 2 (H2O) 2](I). The magnetic static field …
coordinated high-spin Co (II) complex cis-[Co (hfac) 2 (H2O) 2](I). The magnetic static field …
Neutral cobalt (ii)-bis (benzimidazole) pyridine field-induced single-ion magnets for surface deposition
J Juráková, OF Fellner, S Schlittenhardt… - Inorganic Chemistry …, 2023 - pubs.rsc.org
Two novel hexacoordinated Co (II)-based single-ion magnets were prepared and
characterised. Both neutral complexes feature metal-centred coordination with one terminal …
characterised. Both neutral complexes feature metal-centred coordination with one terminal …