The exploitation of noncovalent interactions (NCIs) is emerging as a vital handle in tackling
broad stereoselectivity challenges in synthesis. In particular, there has been significant …

Neuropathic pain is a refractory disease that occurs across the world and pharmacotherapy
has limited efficacy and/or safety. This disease imposes a significant burden on both the …

The synthesis and conformational analysis of a series of phenyl 2, 3, 6-tri-O-benzyl-β-d-thio
galacto-and glucopyranosides and their 6 S-deuterio isotopomers, with systematic variation …

Unsaturated monosaccharides expand the scope of reactivities in a sugar, directly leading to
the development of newer methodologies, molecular structures and functional entities. The …

We herein report a convenient and highly stereocontrolled approach for rare and vital ᴅ-talo
and ᴅ-gulo sugars directly from economical ᴅ-galactal through dual ruthenium-catalysis …

Seven-membered cyclic sugars are known as septanoses and septanosides. Whereas
furanose and pyranose structures represent the known naturally available sugars, the seven …

Previously, our group constructed several immunogens utilizing oxime linkage to conjugate
a T-cell stimulatory zwitterionic polysaccharide PS A1 and tumor associated carbohydrate …

Carbohydrate-based oxepines are seven-membered-ring oxacycles containing an enol
ether moiety. These compounds have been used as intermediates in the preparation of …

A three-step approach to enantiomerically pure 3-aminoseptanoside derivatives by addition
of lithiated methoxyallene to δ-silylated aldopentose-derived nitrones, followed by Brønsted …

Cyclopropylmethylidene has been developed as a versatile protecting group for
carbohydrate synthesis. It can be formed by acid-catalyzed acetalization between …