Catalytic strategies and mechanism analysis orbiting the center of critical intermediates in lignin depolymerization

C Zhang, X Shen, Y Jin, J Cheng, C Cai… - Chemical …, 2023 - ACS Publications
Lignin, as a precious resource given to mankind by nature with abundant functional aromatic
structures, has drawn much attention in the recent decade from academia to industry …

Downstream processing of lignin derived feedstock into end products

SS Wong, R Shu, J Zhang, H Liu, N Yan - Chemical Society Reviews, 2020 - pubs.rsc.org
Despite the enormous research efforts in recent years regarding lignin depolymerisation and
functionalisation, few commercial products are available. This review provides a summary …

Guidelines for performing lignin-first biorefining

MM Abu-Omar, K Barta, GT Beckham… - Energy & …, 2021 - pubs.rsc.org
The valorisation of the plant biopolymer lignin is now recognised as essential to enabling
the economic viability of the lignocellulosic biorefining industry. In this context, the “lignin …

Techno-economic analysis and life cycle assessment of a biorefinery utilizing reductive catalytic fractionation

AW Bartling, ML Stone, RJ Hanes, A Bhatt… - Energy & …, 2021 - pubs.rsc.org
Reductive catalytic fractionation (RCF) is a promising approach to fractionate lignocellulose
and convert lignin to a narrow product slate. To guide research towards commercialization …

Reductive catalytic fractionation: state of the art of the lignin-first biorefinery

T Renders, G Van den Bossche, T Vangeel… - Current opinion in …, 2019 - Elsevier
Reductive catalytic fractionation (RCF) of lignocellulose is an emerging biorefinery scheme
that combines biomass fractionation with lignin depolymerisation. Central to this scheme is …

Selective hydrogenolysis of catechyl lignin into propenylcatechol over an atomically dispersed ruthenium catalyst

S Wang, K Zhang, H Li, LP Xiao, G Song - Nature Communications, 2021 - nature.com
C-lignin is a homo-biopolymer, being made up of caffeyl alcohol exclusively. There is
significant interest in developing efficient and selective catalyst for depolymerization of C …

Greener routes to biomass waste valorization: Lignin transformation through electrocatalysis for renewable chemicals and fuels production

M Garedew, F Lin, B Song, TM DeWinter… - …, 2020 - Wiley Online Library
Lignin valorization is essential for biorefineries to produce fuels and chemicals for a
sustainable future. Today's biorefineries pursue profitable value propositions for cellulose …

Reductive catalytic fractionation as a novel pretreatment/lignin-first approach for lignocellulosic biomass valorization: A review

M Jindal, P Uniyal, B Thallada - Bioresource Technology, 2023 - Elsevier
Presently, the use of lignocellulosic biomass is mainly focused on creating pulp/paper,
energy, sugars and bioethanol from the holocellulose component, leaving behind lignin to …

Reductive catalytic fractionation of pine wood: elucidating and quantifying the molecular structures in the lignin oil

K Van Aelst, E Van Sinay, T Vangeel, E Cooreman… - Chemical …, 2020 - pubs.rsc.org
In-depth structural analysis of biorefined lignin is imperative to understand its
physicochemical properties, essential for its efficient valorization to renewable materials and …

Differences in S/G ratio in natural poplar variants do not predict catalytic depolymerization monomer yields

EM Anderson, ML Stone, R Katahira, M Reed… - Nature …, 2019 - nature.com
The ratio of syringyl (S) and guaiacyl (G) units in lignin has been regarded as a major factor
in determining the maximum monomer yield from lignin depolymerization. This limit arises …