The use of transition metals to catalyse the addition of hydridoboranes to unsaturated
organic molecules was initially realised several decades ago. Although this area of …

Geometrical E→ Z alkene isomerization is intimately entwined in the historical fabric of
organic photochemistry and is enjoying a renaissance (Roth et al. Angew. Chem., Int. Ed …

Stereochemical enrichment of a racemic mixture by deracemization must overcome
unfavorable entropic effects as well as the principle of microscopic reversibility; recently …

Substantial advances in enantioconvergent C (sp3)–C (sp3) bond formations have been
made with nickel-catalyzed cross-coupling of racemic alkyl electrophiles with organometallic …

Organosilanes are of vital importance for modern human society, having found widespread
applications in functional materials, organic synthesis, drug discovery and life sciences …

Fully automated synthetic chemistry would substantially change the field by providing broad
on-demand access to small molecules. However, the reactions that can be run …

Organoboron reagents are one of the most widely studied and applied classes of reagent
throughout organic synthesis and catalysis. Not only are these reagents integral to many of …

The formation of highly enantioenriched boronic esters through both stoichiometric and
catalytic methods has received much attention over the past decade. Accordingly, the …

Carbenes are highly enabling reactive intermediates that facilitate a diverse range of
otherwise inaccessible chemistry, including small-ring formation and insertion into strong σ …

Photoredox catalysis has emerged as a powerful tool for the synthetic chemist to access
challenging targets and to generate new structural complexity. This review focuses on the …